The arylation of bicyclic oxathiane glycosyl donors has been achieved using benzyne generated in situ from 1-aminobenzotriazole (1-ABT) and lead tetraacetate. Following sulfur arylation, glycosylation of acetate ions proceeded with high levels of stereoselectivity to afford α-glycosyl acetates in a ‘one-pot’ reaction, even in the presence of alternative acceptor alcohols
Aryl glycosides represent a group of molecules with immense biological applications and implications...
This article describes the development of alkylated S-benzimidazolyl (SBiz) imidates as versatile bu...
The development of a procedure for the one-pot synthesis of glycosyl benzoates directly from unprote...
The arylation of bicyclic oxathiane glycosyl donors has been achieved using benzyne generated in sit...
A bicyclic glycosyl donor is activated as an arylsulfonium ion and used to synthesise alpha-glycosid...
Known methods of generating arynes, and their chemical reactions, have been classified, and some new...
Benzoylated rhamnosyl and lactosyl trichloacetimidate donors were used in glycosylation reactions wi...
Our research group first took an interest in the unique reactivity of benzyne in an attempt to emplo...
Within 14 years of the seminal experiments of J. D. Roberts leading to the first proposal of the st...
ABSTRACT: A base-promoted formal arylation of benzo[d]-oxazoles with acyl chloride was achieved in m...
Tricyclic biaryls were formed by a direct arylation reaction conducted in the presence of catalytic ...
It is over 100 years since scientists first postulated the existence of arynes as reactive intermedi...
This document is the Accepted Manuscript version of a Published Work that appeared in final form in ...
A regioselective and concomitant transfer of thiocyanate (−SCN) and aroyl/acyl (−COR) groups from ar...
The reactions of arylacetic acid esters with tertiary arylamines in the presence of TiCl4 give α-ary...
Aryl glycosides represent a group of molecules with immense biological applications and implications...
This article describes the development of alkylated S-benzimidazolyl (SBiz) imidates as versatile bu...
The development of a procedure for the one-pot synthesis of glycosyl benzoates directly from unprote...
The arylation of bicyclic oxathiane glycosyl donors has been achieved using benzyne generated in sit...
A bicyclic glycosyl donor is activated as an arylsulfonium ion and used to synthesise alpha-glycosid...
Known methods of generating arynes, and their chemical reactions, have been classified, and some new...
Benzoylated rhamnosyl and lactosyl trichloacetimidate donors were used in glycosylation reactions wi...
Our research group first took an interest in the unique reactivity of benzyne in an attempt to emplo...
Within 14 years of the seminal experiments of J. D. Roberts leading to the first proposal of the st...
ABSTRACT: A base-promoted formal arylation of benzo[d]-oxazoles with acyl chloride was achieved in m...
Tricyclic biaryls were formed by a direct arylation reaction conducted in the presence of catalytic ...
It is over 100 years since scientists first postulated the existence of arynes as reactive intermedi...
This document is the Accepted Manuscript version of a Published Work that appeared in final form in ...
A regioselective and concomitant transfer of thiocyanate (−SCN) and aroyl/acyl (−COR) groups from ar...
The reactions of arylacetic acid esters with tertiary arylamines in the presence of TiCl4 give α-ary...
Aryl glycosides represent a group of molecules with immense biological applications and implications...
This article describes the development of alkylated S-benzimidazolyl (SBiz) imidates as versatile bu...
The development of a procedure for the one-pot synthesis of glycosyl benzoates directly from unprote...
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