The two most metal-rich lanthanide antimony phases known were obtained from high-temperature solid state syntheses, that for Tm3Sb being of greater difficulty because of its apparent incongruent melting. The Tm3Sb phase crystallizes in the tetragonal space group P42/n (No. 86) with a Ti3P-type (Pearson: tP32) structure, a = 12.2294(5) Å, c = 5.9852(5) Å, and Z = 8. The phase Lu7Sb3 exhibits a Sc7As3-type tetragonal structure, I4/mcm (No. 140) (tI56), with a = 15.5974(7) Å, c = 8.8130(7) Å, and Z = 8. Both structures are described in terms of compact arrays of condensed chains of metal polyhedra (tetrahedral, tetrahedral star, trigonal prismatic, cubic) together with six- to nine-coordinate Sb in metal polyhedra. Magnetic susceptibility data...
Single crystals of YbAlB4 were grown in excess Al flux. Plate- and needle-shaped crystals were found...
Synthesis, crystal structure, thermal stability, and electronic band structure of four new metal ant...
The ternary polar intermetallic phase Mg<SUB>5.231(8)</SUB>Sm<SUB>0.769(8)</SUB>Sb<SUB>4</SUB> has b...
The two most metal-rich lanthanide antimony phases known were obtained from high-temperature solid s...
The two most metal-rich lanthanide antimony phases known were obtained from high-temperature solid s...
International audienceThe ternary antimonides Ln3Pd8Sb4 (Ln=Y, Gd, Tb, Dy, Ho, Er, Tm) have been syn...
International audienceA number of new quaternary rare-earth pyrochlores Ln2BSbO7 are reported with L...
Five new analogues of the β-CeNiSb3 family have been synthesized and found to be LnNi(Sn,Sb)3 and is...
The ternary polar intermetallic phase Mg5.231(8)Sm0.769(8)Sb4 has been obtained from solid-state rea...
Solvothennal and hydrothennal synthesis is widely applied in the generation of . metastable crystall...
Reactions of the elements in welded Ta containers at 875-1050°C produce the black brittle compounds ...
Single crystals of LnFeSb3 (Ln = Pr, Nd, Sm, Gd, and Tb) have been grown from excess Sb flux. The cr...
This dissertation describes the crystal growth, chemical structures, and efforts made towards the un...
This thesis describes the synthesis and characterisation of phases related to schafarzikite (FeSb\(_...
Single crystals of YbAlB4 were grown in excess Al flux. Plate- and needle-shaped crystals were found...
Single crystals of YbAlB4 were grown in excess Al flux. Plate- and needle-shaped crystals were found...
Synthesis, crystal structure, thermal stability, and electronic band structure of four new metal ant...
The ternary polar intermetallic phase Mg<SUB>5.231(8)</SUB>Sm<SUB>0.769(8)</SUB>Sb<SUB>4</SUB> has b...
The two most metal-rich lanthanide antimony phases known were obtained from high-temperature solid s...
The two most metal-rich lanthanide antimony phases known were obtained from high-temperature solid s...
International audienceThe ternary antimonides Ln3Pd8Sb4 (Ln=Y, Gd, Tb, Dy, Ho, Er, Tm) have been syn...
International audienceA number of new quaternary rare-earth pyrochlores Ln2BSbO7 are reported with L...
Five new analogues of the β-CeNiSb3 family have been synthesized and found to be LnNi(Sn,Sb)3 and is...
The ternary polar intermetallic phase Mg5.231(8)Sm0.769(8)Sb4 has been obtained from solid-state rea...
Solvothennal and hydrothennal synthesis is widely applied in the generation of . metastable crystall...
Reactions of the elements in welded Ta containers at 875-1050°C produce the black brittle compounds ...
Single crystals of LnFeSb3 (Ln = Pr, Nd, Sm, Gd, and Tb) have been grown from excess Sb flux. The cr...
This dissertation describes the crystal growth, chemical structures, and efforts made towards the un...
This thesis describes the synthesis and characterisation of phases related to schafarzikite (FeSb\(_...
Single crystals of YbAlB4 were grown in excess Al flux. Plate- and needle-shaped crystals were found...
Single crystals of YbAlB4 were grown in excess Al flux. Plate- and needle-shaped crystals were found...
Synthesis, crystal structure, thermal stability, and electronic band structure of four new metal ant...
The ternary polar intermetallic phase Mg<SUB>5.231(8)</SUB>Sm<SUB>0.769(8)</SUB>Sb<SUB>4</SUB> has b...