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Synthesis of a metallophilic metallamacrocycle: a Hg<SUP>II</SUP>···Cu<SUP>I</SUP>···Hg<SUP>II</SUP>···Hg<SUP>II</SUP>···Cu<SUP>I</SUP>···Hg<SUP>II</SUP> interaction

  • Patel, Upali
  • Singh, Harkesh B.
  • Wolmershäuser, Gotthelf
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Publication date
March 2005
Icon DOI
10.1002/anie.200462487/abstract
Publisher
Wiley

Abstract

Complexation of a CuI ion in a mercuramacrocycle demonstrates the potential of metal-metal interactions in a preorganized system to trap metal ions. The molecular structure of the CuI complex is presented and shows Hg&#183;&#183;&#183;Cu heterometallic and Hg&#183;&#183;&#183;Hg homometallic d10&#183;&#183;&#183;d10 interactions (see figure)

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