A novel application of Fe–Zn double metal cyanide complexes as solid, acid catalysts for regioselective synthesis of β-amino alcohols under solvent-free conditions via ring-opening of epoxides with amines is reported for the first time. The conversion of epoxides to β-amino alcohols is nearly 100%. In the reaction with styrene oxide, regioselective β-amino alcohol formation is higher with aromatic than with aliphatic amines. Strong Lewis acidic Zn2+ ions in the catalyst are probably the active sites in this reaction
Aryl-substituted amino alcohols are privileged scaffolds in medicinal chemistry and natural products...
Lanthanide(lll) trifluoromethanesulfonates (triflates), such as Yb(OTf)3, Nd(OTf)3 and Gd(OTf)3, cat...
Zeolite encapsulated amino acid complexes such as Fe-proline, Fe-histidine and Cu-valine have shown ...
A novel application of Fe–Zn double metal cyanide complexes as solid, acid catalysts for regioselect...
Commercially available zinc(II) perchlorate hexahydrate [Zn(ClO<SUB>4</SUB>)<SUB>2</SUB>·6H<SUB>2</S...
A simple, efficient, and environmentally benign approach for the synthesis of β-amino alcohols is he...
Sulfated zirconia and SZ/MCM-41 were used as catalysts for the synthesis of β-aminoalcohols via epox...
Zinc oxide (ZnO) catalyses the nucleophilic opening of epoxide rings by amines leading to the effici...
ly iv ator 31 M ne 2Fe–Zn double-metal cyanide complexes are currently used as catalysts for the rin...
The catalytic aminolysis of epoxides can lead to a large number of β‐amino alcohols which are of par...
The goal of this research was to explore new opportunities for the atom efficient synthesis of amine...
Given the success of organic ligands in transition metal catalysis, we incorporated the chirality of...
ß-amino alcohols are common substructures in many biologically active compounds and can also be used...
A study aimed at the synthesis and structure optimization of new, efficient, optically active β-amin...
Silica gel (60–120 mesh) efficiently catalyses the opening of epoxides by amines at rt under solvent...
Aryl-substituted amino alcohols are privileged scaffolds in medicinal chemistry and natural products...
Lanthanide(lll) trifluoromethanesulfonates (triflates), such as Yb(OTf)3, Nd(OTf)3 and Gd(OTf)3, cat...
Zeolite encapsulated amino acid complexes such as Fe-proline, Fe-histidine and Cu-valine have shown ...
A novel application of Fe–Zn double metal cyanide complexes as solid, acid catalysts for regioselect...
Commercially available zinc(II) perchlorate hexahydrate [Zn(ClO<SUB>4</SUB>)<SUB>2</SUB>·6H<SUB>2</S...
A simple, efficient, and environmentally benign approach for the synthesis of β-amino alcohols is he...
Sulfated zirconia and SZ/MCM-41 were used as catalysts for the synthesis of β-aminoalcohols via epox...
Zinc oxide (ZnO) catalyses the nucleophilic opening of epoxide rings by amines leading to the effici...
ly iv ator 31 M ne 2Fe–Zn double-metal cyanide complexes are currently used as catalysts for the rin...
The catalytic aminolysis of epoxides can lead to a large number of β‐amino alcohols which are of par...
The goal of this research was to explore new opportunities for the atom efficient synthesis of amine...
Given the success of organic ligands in transition metal catalysis, we incorporated the chirality of...
ß-amino alcohols are common substructures in many biologically active compounds and can also be used...
A study aimed at the synthesis and structure optimization of new, efficient, optically active β-amin...
Silica gel (60–120 mesh) efficiently catalyses the opening of epoxides by amines at rt under solvent...
Aryl-substituted amino alcohols are privileged scaffolds in medicinal chemistry and natural products...
Lanthanide(lll) trifluoromethanesulfonates (triflates), such as Yb(OTf)3, Nd(OTf)3 and Gd(OTf)3, cat...
Zeolite encapsulated amino acid complexes such as Fe-proline, Fe-histidine and Cu-valine have shown ...