First example of a hydrated monoorganotin cation: Synthesis and structure of [{PhSn(H2O)3(μ -OH)}2][{1,5-C10H6-(SO3)2}2]

Chandrasekhar, Vadapalli
Singh, Puja

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Publication date

January 2008

DOI

10.1021/om800972m

Publisher

American Chemical Society (ACS)

Abstract

The reaction of Ph2SnO with naphthalene-1,5-disulfonic acid tetrahydrate affords, through a Sn-aryl bond cleavage process, the first example of a hydrated monoorganotin cation, [{PhSn(H2O)3(μ -OH)}2][{1,5-C10H6-(SO3)2}2]. The structural elucidation of the latter showed that it contained a tetracationic dinuclear unit where the two tin atoms are bridged by two hydroxide ligands and each tin is hydrated with three molecules of water. Intermolecular hydrogen-bonding interactions between the water molecules and the disulfonate anions result in a pillared three-dimensional network

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First example of a hydrated monoorganotin cation: Synthesis and structure of [{PhSn(H<SUB>2</SUB>O)<SUB>3</SUB>(μ -OH)}<SUB>2</SUB>][{1,5-C<SUB>10</SUB>H<SUB>6</SUB>-(SO<SUB>3</SUB>)<SUB>2</SUB>}<SUB>2</SUB>]

Abstract

Extracted data

First example of a hydrated monoorganotin cation: Synthesis and structure of [{PhSn(H<SUB>2</SUB>O)<SUB>3</SUB>(μ -OH)}<SUB>2</SUB>][{1,5-C<SUB>10</SUB>H<SUB>6</SUB>-(SO<SUB>3</SUB>)<SUB>2</SUB>}<SUB>2</SUB>]

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First example of a hydrated monoorganotin cation: Synthesis and structure of [{PhSn(H<SUB>2</SUB>O)<SUB>3</SUB>(&#956; -OH)}<SUB>2</SUB>][{1,5-C<SUB>10</SUB>H<SUB>6</SUB>-(SO<SUB>3</SUB>)<SUB>2</SUB>}<SUB>2</SUB>]

Abstract

Extracted data

First example of a hydrated monoorganotin cation: Synthesis and structure of [{PhSn(H<SUB>2</SUB>O)<SUB>3</SUB>(&#956; -OH)}<SUB>2</SUB>][{1,5-C<SUB>10</SUB>H<SUB>6</SUB>-(SO<SUB>3</SUB>)<SUB>2</SUB>}<SUB>2</SUB>]

Abstract

Extracted data

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First example of a hydrated monoorganotin cation: Synthesis and structure of [{PhSn(H<SUB>2</SUB>O)<SUB>3</SUB>(μ -OH)}<SUB>2</SUB>][{1,5-C<SUB>10</SUB>H<SUB>6</SUB>-(SO<SUB>3</SUB>)<SUB>2</SUB>}<SUB>2</SUB>]

First example of a hydrated monoorganotin cation: Synthesis and structure of [{PhSn(H<SUB>2</SUB>O)<SUB>3</SUB>(μ -OH)}<SUB>2</SUB>][{1,5-C<SUB>10</SUB>H<SUB>6</SUB>-(SO<SUB>3</SUB>)<SUB>2</SUB>}<SUB>2</SUB>]