Cobalt catalysts promoted with cerium and lanthanum applied to partial oxidation of methane reactions

Catalysts of Co/Mg/Al promoted with Ce and La were tested in the catalytic partial oxidation of methane (POM) reaction. The addition of promoters was made by anion-exchange. X-ray diffraction (XRD) confirmed the formation of hydrotalcite phase for precursors. The mixed oxides were characterized as a mixture of Co3O4, periclase (Co, Al)MgO and/or spinel structure (Mg, Co)Al2O4. In the catalytic POM reaction over the promoted catalysts, a reduction in the carbon formation rate was found. (c) 2008 Elsevier B.V. All rights reserved.Brazilian federal research funding council (FINEP)Financiadora de Estudos e Projetos (FINEP)CNPqConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)CAPESFAPESPFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP