Nonlinear dynamics determines the thermodynamic instability of condensed matter in vacuo

Condensed matter is thermodynamically unstable in a vacuum. That is what thermodynamics tells us through the relation showing that condensed matter at temperatures above absolute zero always has non-zero vapour pressure. This instability implies that at low temperatures energy must not be distributed equally among atoms in the crystal lattice but must be concentrated. In dynamical systems such concentrations of energy in localized excitations are well known in the form of discrete breathers, solitons and related nonlinear phenomena. It follows that to satisfy thermodynamics such localized excitations must exist in systems of condensed matter at arbitrarily low temperature and as such the nonlinear dynamics of condensed matter is crucial for its thermodynamics. This article is part of the theme issue 'Stokes at 200 (Part 1)'.I acknowledge the financial support of the Spanish MINCINN project FIS2016-77692-C2-2-P