Treatment of benzoin with cyclopentadiene in NaOH/MEOH and pyrrolidine/ MEOH gave benzil via an Oppenauer oxidation, rather than the desired 6-phenyl-6-phenylmethanolfulvene. Treatment of (+)-(lS)-10- camphorsulfonamide and (-)-camphorsulfonimine with cyclopentadiene in NaOH/MEOH and pyrrolidine/ MEOH led to an equilibrium mixture of 10- camphorsulfonamide and (-)-camphorsulfonimine, rather than the desired Camphorsulfonamidefulvene. Treatment of (+)-(! R)-camphor with cyclopentadiene and pyrrolidine/MEOH resulted in a high yield recovery of the starting material and none of the desired camphorfulvene
The asymmetric allylation of carbonyl compounds has been extensively studied.However, many reported ...
Simple enantioselective synthesis of 6,6-disubstituted pentafulvenes bearing chiral pendant hydroxy ...
Simple enantioselective synthesis of 6,6-disubstituted pentafulvenes bearing chiral pendant hydroxy ...
The proposal to synthesize a camphor sulfinamide reagent using 2-bornanethiol was initiated. A novel...
The cyclopentyl compounds 113,114, and 115 and their enantiomers ent-113, ent-114 and ent-115 repres...
Several camphor and pinane derivatives have been synthesised and evaluated for use as chiral auxilia...
The use of (-)-camphor (ent-9) as an enantiopure intermediate in pseudoguaianolide and limonoid syn...
The use of (-)-camphor (ent-9) as an enantiopure intermediate in pseudoguaianolide and limonoid syn...
[[abstract]]ABSTRACT Design and Synthesis of Novel Camphor Derived Chiral Auxiliary/Ligands and Thei...
This thesis, entitled "The use of camphor in sesquiter-penoid synthesis", consists of three chapters...
The investigation has been focussed largely on the chemistry and stereo-directing potential of camph...
Thesis (M.Sc.)-University of KwaZulu-Natal, Durban, 2006.Chiral crown ethers have recently been show...
Several camphor and pinane derivatives have been synthesised and evaluated for use as chiral auxilia...
Chapter 1 Overview of enantioselective desymmetrisations of prochiral and mesocompounds A molecule i...
Chapter 1 Overview of enantioselective desymmetrisations of prochiral and mesocompounds A molecule i...
The asymmetric allylation of carbonyl compounds has been extensively studied.However, many reported ...
Simple enantioselective synthesis of 6,6-disubstituted pentafulvenes bearing chiral pendant hydroxy ...
Simple enantioselective synthesis of 6,6-disubstituted pentafulvenes bearing chiral pendant hydroxy ...
The proposal to synthesize a camphor sulfinamide reagent using 2-bornanethiol was initiated. A novel...
The cyclopentyl compounds 113,114, and 115 and their enantiomers ent-113, ent-114 and ent-115 repres...
Several camphor and pinane derivatives have been synthesised and evaluated for use as chiral auxilia...
The use of (-)-camphor (ent-9) as an enantiopure intermediate in pseudoguaianolide and limonoid syn...
The use of (-)-camphor (ent-9) as an enantiopure intermediate in pseudoguaianolide and limonoid syn...
[[abstract]]ABSTRACT Design and Synthesis of Novel Camphor Derived Chiral Auxiliary/Ligands and Thei...
This thesis, entitled "The use of camphor in sesquiter-penoid synthesis", consists of three chapters...
The investigation has been focussed largely on the chemistry and stereo-directing potential of camph...
Thesis (M.Sc.)-University of KwaZulu-Natal, Durban, 2006.Chiral crown ethers have recently been show...
Several camphor and pinane derivatives have been synthesised and evaluated for use as chiral auxilia...
Chapter 1 Overview of enantioselective desymmetrisations of prochiral and mesocompounds A molecule i...
Chapter 1 Overview of enantioselective desymmetrisations of prochiral and mesocompounds A molecule i...
The asymmetric allylation of carbonyl compounds has been extensively studied.However, many reported ...
Simple enantioselective synthesis of 6,6-disubstituted pentafulvenes bearing chiral pendant hydroxy ...
Simple enantioselective synthesis of 6,6-disubstituted pentafulvenes bearing chiral pendant hydroxy ...