Mechanistic information has been obtained for the Wagner Meerwein rearrangement of cubylcarbinyl p nitroben zoate from kinetic data gained using lithium perchlorate as added salt. Further attempts have been made to describe the rearrangement of cubylcarbinol using various concentra�tions of perchloric acid. The rate of rearrangement in this solvent has been shown to be comparable to that when aqueous hydrogen bromide is solvent
Includes bibliographical references.Includes illustrations.The solvolysis of methyl perchlorate has ...
SECTION I: A study of the solvolytic behaviour of exo- and endo-1,5-dimethylbicyclo (3,3,1) nonan-9-...
Addition of inorganic chlorides and perchlorates into the reaction mixture in water leads to a signi...
In continuation of rearrangement reactions of organometallic compounds, it was desirable to ascertai...
The purpose of this research was to seek evidence for the ion-pair mechanism in tertiary substrates ...
The barriers to nitrogen inversion were determined for several l-methyl-2-azabicyclo [2.1.1] heptyl ...
The bromide ion catalysed rearrangement reaction of ⍺-methylallyl bromide in acetone was studied by ...
The alkali metal salts of 1,5-hexadien-3-ols undergo accelerated Cope rearrangements to the enolate...
Neoclovene, a product from acid-catalysed rearrangement of caryophyllene, has been synthesised in su...
The extents of isotope-position rearrangement have been determined in solvolyses of exo- and endo-no...
A quantitative estimation of the products of the rearrangement of N-chlorobenzanilide, catalysed by ...
1-Methylcyclopropylcarbinylamine and 1-methylcyclobutylamine on treatment with aqueous nitrous acid ...
In Chapter I of this dissertation, the Skattebol-type rearrangement (in THF solution at -78(DEGREES)...
Part I. The pmr spectrum of 1,2-dimethylnorbornyl cation indicates that the Wagner-Meerwein rear...
The solvolysis of cyclopropylcarbinyl chloride in 80% ethanol is attended by substantial rearrangeme...
Includes bibliographical references.Includes illustrations.The solvolysis of methyl perchlorate has ...
SECTION I: A study of the solvolytic behaviour of exo- and endo-1,5-dimethylbicyclo (3,3,1) nonan-9-...
Addition of inorganic chlorides and perchlorates into the reaction mixture in water leads to a signi...
In continuation of rearrangement reactions of organometallic compounds, it was desirable to ascertai...
The purpose of this research was to seek evidence for the ion-pair mechanism in tertiary substrates ...
The barriers to nitrogen inversion were determined for several l-methyl-2-azabicyclo [2.1.1] heptyl ...
The bromide ion catalysed rearrangement reaction of ⍺-methylallyl bromide in acetone was studied by ...
The alkali metal salts of 1,5-hexadien-3-ols undergo accelerated Cope rearrangements to the enolate...
Neoclovene, a product from acid-catalysed rearrangement of caryophyllene, has been synthesised in su...
The extents of isotope-position rearrangement have been determined in solvolyses of exo- and endo-no...
A quantitative estimation of the products of the rearrangement of N-chlorobenzanilide, catalysed by ...
1-Methylcyclopropylcarbinylamine and 1-methylcyclobutylamine on treatment with aqueous nitrous acid ...
In Chapter I of this dissertation, the Skattebol-type rearrangement (in THF solution at -78(DEGREES)...
Part I. The pmr spectrum of 1,2-dimethylnorbornyl cation indicates that the Wagner-Meerwein rear...
The solvolysis of cyclopropylcarbinyl chloride in 80% ethanol is attended by substantial rearrangeme...
Includes bibliographical references.Includes illustrations.The solvolysis of methyl perchlorate has ...
SECTION I: A study of the solvolytic behaviour of exo- and endo-1,5-dimethylbicyclo (3,3,1) nonan-9-...
Addition of inorganic chlorides and perchlorates into the reaction mixture in water leads to a signi...