International audienceSix Mn-Schiff base complexes, [Mn(X-salpn)]0/+ (salpn = 1,3-bis(sal-ic-ylidenamino)propane, X = H [1], 5-Cl [2], 2,5-F2 [3], 3,5-Cl2 [4], 5-NO2 [5], 3,5-(NO2)2 [6]), were synthesized and characterized in solution, and second-sphere effects on their electrochemical and spectroscopic properties were analyzed. The six complexes catalyze the dismutation of superoxide with catalytic rate constants in the range 0.65 to 1.54 × 106 M–1 s–1 obtained through the nitro blue tetrazolium photoreduction inhibition superoxide dismutases assay, in aqueous medium of pH 7.8. In solution, these compounds possess two labile solvent molecules in the axial positions favoring coordination of the highly nucleophilic O2•– to the metal center. ...
This study describes the synthesis, crystal structure and antioxidant activity of manganese(III) com...
Potentially hexadentate N2O4 donor Schiff base ligands N,N0-bis(3-ethoxysalicylidenimino)-1,2-diamin...
Manganese catalases (MnCAT) and superoxide dismutases (MnSOD) deplete hydrogen peroxide and superoxi...
International audienceSix Mn-Schiff base complexes, [Mn(X-salpn)]0/+ (salpn = 1,3-bis(sal-ic-ylidena...
International audienceSix Mn-Schiff base complexes, [Mn(X-salpn)]0/+ (salpn = 1,3-bis(sal-ic-ylidena...
Six Mn-Schiff base complexes, [Mn(X-salpn)]0/+ (salpn = 1,3-bis(sal-ic-ylidenamino)propane, X = H...
Six Mn-Schiff base complexes, [Mn(X-salpn)]0/+ (salpn = 1,3-bis(sal-ic-ylidenamino)propane, X = H [...
This dissertation explores the reactivities, properties and structures of manganese complexes as mod...
International audienceTwo crystal structures are described in this article: (a) the structure of a m...
International audienceTwo crystal structures are described in this article: (a) the structure of a m...
International audienceTwo crystal structures are described in this article: (a) the structure of a m...
International audienceTwo crystal structures are described in this article: (a) the structure of a m...
Two new MnIII complexes Na[Mn(5-SO3-salpnOH)(H2O)]{dot operator}5H2O (1) and Na[Mn(5-SO3-salpn)(MeOH...
Two crystal structures are described in this article: (a) the structure of a monomeric MnII complex ...
Two mononuclear MnIII complexes [Mn(3,5-F2salpn)(H2O)2][B(C6H5)4]·2H2O (1·2H2O) and [Mn(3,5-Cl2salpn...
This study describes the synthesis, crystal structure and antioxidant activity of manganese(III) com...
Potentially hexadentate N2O4 donor Schiff base ligands N,N0-bis(3-ethoxysalicylidenimino)-1,2-diamin...
Manganese catalases (MnCAT) and superoxide dismutases (MnSOD) deplete hydrogen peroxide and superoxi...
International audienceSix Mn-Schiff base complexes, [Mn(X-salpn)]0/+ (salpn = 1,3-bis(sal-ic-ylidena...
International audienceSix Mn-Schiff base complexes, [Mn(X-salpn)]0/+ (salpn = 1,3-bis(sal-ic-ylidena...
Six Mn-Schiff base complexes, [Mn(X-salpn)]0/+ (salpn = 1,3-bis(sal-ic-ylidenamino)propane, X = H...
Six Mn-Schiff base complexes, [Mn(X-salpn)]0/+ (salpn = 1,3-bis(sal-ic-ylidenamino)propane, X = H [...
This dissertation explores the reactivities, properties and structures of manganese complexes as mod...
International audienceTwo crystal structures are described in this article: (a) the structure of a m...
International audienceTwo crystal structures are described in this article: (a) the structure of a m...
International audienceTwo crystal structures are described in this article: (a) the structure of a m...
International audienceTwo crystal structures are described in this article: (a) the structure of a m...
Two new MnIII complexes Na[Mn(5-SO3-salpnOH)(H2O)]{dot operator}5H2O (1) and Na[Mn(5-SO3-salpn)(MeOH...
Two crystal structures are described in this article: (a) the structure of a monomeric MnII complex ...
Two mononuclear MnIII complexes [Mn(3,5-F2salpn)(H2O)2][B(C6H5)4]·2H2O (1·2H2O) and [Mn(3,5-Cl2salpn...
This study describes the synthesis, crystal structure and antioxidant activity of manganese(III) com...
Potentially hexadentate N2O4 donor Schiff base ligands N,N0-bis(3-ethoxysalicylidenimino)-1,2-diamin...
Manganese catalases (MnCAT) and superoxide dismutases (MnSOD) deplete hydrogen peroxide and superoxi...