The superlattice structure and self-adaptive performance of C-Ti/MoS2 composite coatings

To improve the self-adaptability of MoS2 coating in different environments, the coatings were doped with functional C and Ti by unbalanced magnetron sputtering system. The clear superlattice structure with minimal modulation period was investigated by High Resolution Transmission Electron Microscope (HRTEM). The co-doped coatings have better mechanical properties due to the special structure and the formation of C-Mo, Ti-S and Ti-O bonds, and better lubrication performance in both high humidity and vacuum than those of the single-doped ones. The doped Ti not only facilitates the formation of the MoS2 (002) basal plane, but also improves the oxidation resistance of the composite film. The degree of friction-induced graphitization on the wear tracks and the quality of transfer films on the wear scars are key factors affecting the lubrication performance of the composite film. In the high-humidity environment, the reasonable doping elements can promote the formation the high-quality transfer film by interacting with H2O water molecules, which will benefit the lubrication of the coating better. Our findings deepen the understanding of MoS2 composite coating and provide a new solution for improving the self-adaptability of the coating