Alumina/Zirconia Micro/Nanocomposites: A new material for biomedical applications with superior sliding wear resistance

In the present investigation, the sliding wear behavior is described for Al2O3/ZrO2 micro/nanocomposites and monolithic alumina of similar grain size under defined conditions of a constant sliding speed and different loads (20–150 N). Nano ZrO2 particles (1.7 vol%) were observed uniformly distributing throughout the composites, and most of them were located within the matrix alumina grains. The wear rate of the alumina and the micro/nanocomposites increased as the contact load increased and a clear transition in friction and wear behavior was observed in both materials. However, the nanocomposite wear resistance at low contact loads was one order of magnitude higher than that of the alumina. In the severe regime, no difference was observed among the materials. The low wear rate (10−7 mm3·(N·m)−1) along with low pullout indicates higher wear resistance of micro/nanocomposites in the mild regime compared with monolithic alumina. Based on the morphological observation of worn surfaces by scanning electron microscope and on residual stress analysis performed by neutron diffraction, some wear mechanisms of Al2O3–ZrO2 micro/nanocomposites are proposed. The high wear resistance of the nanocomposites is discussed in terms of fracture resistance properties and residual stress. Improvements in mechanical and tribological properties of these composites make them promising candidates for biomedical applications.This work was supported by EU under project reference FP6‐515784‐2, by the Spanish Ministry of Science and Technology under project number MAT2006‐10249‐C02‐01 and by the “Dirección General de Universidades e Investigación de la Consejería de Educación y Ciencia de la Comunidad de Madrid” and CSIC under project reference 200660M042. J. F. B. has been supported by Ministry of Science and Technology and CSIC under the “Ramón y Cajal” Program cofinanced by European Social Fund. Beam time was granted by ILL, Exp. No. 7‐01‐163.Peer reviewe