Homoleptic alkenyls of the early transition metals and related compounds

Cardin, C. J.
Cardin, D. J.
Kelly, J. M.
Norton, R. J.
Roy, A.

Publication date

January 1977

DOI

10.1016/S0022-328X(00)93731-8

Publisher

Elsevier BV

ISSN

0022-328X

Abstract

The first stable homoleptic alkenyls of the early transition metals, MRn, (R = C(Ph)=CMe2; M = Ti, Zr, Hf, n = 4; and M = Cr, n = 3) and the related species (C5H5)2MR2 (M = Ti, Zr) and (C5H5)2Zr(Cl)R have been prepared using appropriate organolithium reagents. Cleavage and insertion reactions are reported for the new compounds

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Homoleptic alkenyls of the early transition metals and related compounds

Abstract

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Homoleptic alkenyls of the early transition metals and related compounds

Abstract

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