Synthesis, properties, and X-ray crystal and molecular structures of homoleptic alkenyls of tin and chromium
- Cardin, Christine J.
- Cardin, David J.
- Kelly, John M.
- Norton, Reginald J.
- Roy, Abhijit
- Hathaway, Brian J.
- King, Trevor J.
DOIAbstract
Reaction of Li(CPhCMe2) with SnCl4 or CrCl3·3thf (thf = tetrahydrofuran) affords the isoleptic compounds Sn(CPhCMe2)4 or [Cr(CPhCMe2)4] respectively. The mode of formation and chemical properties are reported for the chromium species, and the structures of the new compounds, both of which have been determined by single-crystal X-ray analysis, are described
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