Hydrogen absorption and 57 Fe Mössbauer effect in UFeGe

Abstract. Hydrogenation of UFeGe transforms the monoclinic type of structure into the orthorhombic (TiNiSi-type) and subsequently to the hexagonal (ZrBeSi-type) structure. It does not induce magnetic order, however magnetic susceptibility is enhanced. The Sommerfeld coefficient γ increases from 12 mJ/mol K 2 in UFeGe to 36 mJ/mol K 2 in UFeGeH 1.7-1.8 (β-hydride). The observed variations of electronic properties are mainly due to the modified geometry of the lattice, characterized by enhanced inter-uranium spacing, and reduced 5f-3d hybridization in the hydrides