In this thesis we provide an introduction to the use of Metal-Organic Frameworks (MOFs) for hydrogen storage and for the separation of hydrogen isotopologues, H2 and D2. MOFs are a class of materials comprised of `building-block’ metal-oxide clusters connected by organic ligands, which have the capacity to adsorb molecules such as hydrogen through weak, physisorptive mechanisms. We provide some background on the quantum mechanical structure of hydrogen isotopologues, the structure of a few state-of-the-art MOFs, the quantum mechanics of infrared spectroscopy, and the desorption dynamics of adsorbates generally. We provide a description of the experimental apparatus and procedure used in this work to acquire thermal desorption (TD) and simul...
Hydrogen storage is among the most demanding challenges in the hydrogen-based energy cycle. One prop...
Hydrogen storage is among the most demanding challenges in the hydrogen-based energy cycle. One prop...
Experimental hydrogen isotherms on several metal-organic frameworks (IRMOF-1, IRMOF-3, IRMOF-9, ZIF-...
In this thesis we provide an introduction to the use of Metal-Organic Frameworks (MOFs) for hydrogen...
A body of research has recently formed around the study of hydrogen adsorption in Metal-Organic Fram...
In this thesis we present our research on hydrogen isotope separation using metal-organic frameworks...
The role of exposed metal sites in increasing the H2 storage performances in metal-organic framework...
In this thesis we examine the hydrogen storage properties of four different materials. Because of th...
Author Institution: Department of Physics and Astronomy, Oberlin College; Oberlin, OH 44074; Depart...
The quantum sieving effect between D2 and H2 is examined for a series of metal–organic frameworks (M...
Separating gaseous mixtures that consist of very similar size is one of the critical issues in moder...
Separation of hydrogen isotopes is of great importance to produce highly pure hydrogen isotopes for ...
Diffuse reflectance infrared (IR) spectroscopy performed over a wide temperature range (35–298 K) is...
To maximize reversible H_2 storage near room temperature and modest pressures, we propose Li doping ...
Highly pure deuterium is an irreplaceable raw material for both industrial and scientific research, ...
Hydrogen storage is among the most demanding challenges in the hydrogen-based energy cycle. One prop...
Hydrogen storage is among the most demanding challenges in the hydrogen-based energy cycle. One prop...
Experimental hydrogen isotherms on several metal-organic frameworks (IRMOF-1, IRMOF-3, IRMOF-9, ZIF-...
In this thesis we provide an introduction to the use of Metal-Organic Frameworks (MOFs) for hydrogen...
A body of research has recently formed around the study of hydrogen adsorption in Metal-Organic Fram...
In this thesis we present our research on hydrogen isotope separation using metal-organic frameworks...
The role of exposed metal sites in increasing the H2 storage performances in metal-organic framework...
In this thesis we examine the hydrogen storage properties of four different materials. Because of th...
Author Institution: Department of Physics and Astronomy, Oberlin College; Oberlin, OH 44074; Depart...
The quantum sieving effect between D2 and H2 is examined for a series of metal–organic frameworks (M...
Separating gaseous mixtures that consist of very similar size is one of the critical issues in moder...
Separation of hydrogen isotopes is of great importance to produce highly pure hydrogen isotopes for ...
Diffuse reflectance infrared (IR) spectroscopy performed over a wide temperature range (35–298 K) is...
To maximize reversible H_2 storage near room temperature and modest pressures, we propose Li doping ...
Highly pure deuterium is an irreplaceable raw material for both industrial and scientific research, ...
Hydrogen storage is among the most demanding challenges in the hydrogen-based energy cycle. One prop...
Hydrogen storage is among the most demanding challenges in the hydrogen-based energy cycle. One prop...
Experimental hydrogen isotherms on several metal-organic frameworks (IRMOF-1, IRMOF-3, IRMOF-9, ZIF-...