Add to ORKGThe trimethylsilylalkyl acetoacetates 1 b and 2 b as well as their carba analogues 1 a and 2 a have been reduced microbiologically by Kloeckera corticis (ATCC 20109), leading to the corresponding ( + )-3(S)-hydroxybutanoates 3b, 4b, 3a, and 4a. The enantiomeric purity was found to be 80% (3a, 3b, 4b) and 65% (4a), respectively. The reduction of lb and 2b is - to our knowledge - the first example for a controlled microbiological transformation of organosilicon substrates
The enantioselective synthesis of organic compounds is one of the great challenges in organic synthe...
The stereoselectivity of the reduction of rac-3-methyl1-(phenylsulfonyl)hexan-2-one (1) to 3-methyl1...
In this study, four bacterial strains were tested for their ability to reduce acetophenones to its c...
Thirty strains of microorganisms (bacteria, yeasts, fungi and green algae) were tested as resting fr...
The -ketoester benzyl acetoacetate was enantioselectively reduced to benzyl (S)-3-hydroxy-butanoate ...
(R)-1,1-Dimethyl-1-sila-cyclohexan-2-ol [(R)-2] was prepared by enantioselective microbial reduction...
The sterospecificities of hydantoinases and N-carbamoyl amino acid amidohydrolases (N-carbamoylases)...
The synthesis of the optically active alkoxymethyl-substituted acetylsilanes (+)-3 and (−)-b was ach...
The production of single enantiomers of \u3b3 and \u3b2-nitroalcohols by microbial bioreduction has ...
Global sales of single enantiomeric drug products are growing at an alarming rate every year. A tota...
Aromatic acylsilanes [Ar-CO-SiMe3; Ar = C6H5,4-ClC6H4, 2-, 3- and 4-OMeC6H4, 3,4-(OMe)2C6H3 and 3,4-...
Microbial synthesis is an important contribution to Green Chemistry and production-integrated enviro...
The major goal of my research is the development of synthetically useful selective biotransformatio...
Several microorganism strains of genera Saccharomyces, Candida, Hansenula, Aspergillus and Lactobaci...
A series of yeasts were used in the bioreductions of aliphatic and aromatic \u3b3- and \u3b4-ketoaci...
The enantioselective synthesis of organic compounds is one of the great challenges in organic synthe...
The stereoselectivity of the reduction of rac-3-methyl1-(phenylsulfonyl)hexan-2-one (1) to 3-methyl1...
In this study, four bacterial strains were tested for their ability to reduce acetophenones to its c...
Thirty strains of microorganisms (bacteria, yeasts, fungi and green algae) were tested as resting fr...
The -ketoester benzyl acetoacetate was enantioselectively reduced to benzyl (S)-3-hydroxy-butanoate ...
(R)-1,1-Dimethyl-1-sila-cyclohexan-2-ol [(R)-2] was prepared by enantioselective microbial reduction...
The sterospecificities of hydantoinases and N-carbamoyl amino acid amidohydrolases (N-carbamoylases)...
The synthesis of the optically active alkoxymethyl-substituted acetylsilanes (+)-3 and (−)-b was ach...
The production of single enantiomers of \u3b3 and \u3b2-nitroalcohols by microbial bioreduction has ...
Global sales of single enantiomeric drug products are growing at an alarming rate every year. A tota...
Aromatic acylsilanes [Ar-CO-SiMe3; Ar = C6H5,4-ClC6H4, 2-, 3- and 4-OMeC6H4, 3,4-(OMe)2C6H3 and 3,4-...
Microbial synthesis is an important contribution to Green Chemistry and production-integrated enviro...
The major goal of my research is the development of synthetically useful selective biotransformatio...
Several microorganism strains of genera Saccharomyces, Candida, Hansenula, Aspergillus and Lactobaci...
A series of yeasts were used in the bioreductions of aliphatic and aromatic \u3b3- and \u3b4-ketoaci...
The enantioselective synthesis of organic compounds is one of the great challenges in organic synthe...
The stereoselectivity of the reduction of rac-3-methyl1-(phenylsulfonyl)hexan-2-one (1) to 3-methyl1...
In this study, four bacterial strains were tested for their ability to reduce acetophenones to its c...