Add to ORKGDie (Acyloxymethyl)diorganylsilane R\(^1\)R\(^2\)Si(H)CH\(_2\)OC(O)R\(^3\) (2a- d) unterliegen einer thermisch induzierten Umlagerung zu den entsprechenden Acyloxy(methyl)diorganylsilanen R\(^1\)R\(^2\)Si(CH\(_3\))OC(O)R\(^3\) (3a- d). Diese Reaktion beinhaltet formal einen Austausch des am Silicium gebundenen Wasserstoffs mit dem am Kohlenstoff gebundenen Acyloxy-Rest. Bezüglich der 1,2- Wasserstoff-Verschiebung konnte experimentell ein intramolekularer Prozeß bewiesen werden.The (acyloxymethyl)diorganylsilanes R\(^1\)R\(^2\)Si(H)CH\(_2\)OC(O)R\(^3\) (2a-d) rearrange to the corresponding acyloxy(methyl)diorganylsilanes R\(^1\)R\(^2\)Si(CH\(_3\))OC(O)R\(^3\) (3a-d). This reaction is formally equivalent to an exchange of the hydrogen bound t...
Ab initio calculations at the CCSD(T)/6-311++G(2d,p)//B3LYP/6-311++G(d,p) level of theory have been ...
The synthesis and the thermal behaviour of the (methylphenylsilyl)methyl carbonates \(CH_3(C_6H_5)Si...
A mechanism for the homogeneous gas-phase decomposition of SiHCl3, SiH2Cl2, and SiH3Cl in hydrogen i...
Twenty silanes of the type R\(^1\)R\(^2\)Si(H)CH\(_2\)OR\(^3\) (A) were syn- and entropy of activati...
It is well known that silicon undergoes facile 1,5-migrations from carbon to carbon. In an attempt t...
The treatment of alkoxymethyl-substituted hydrosilanes with palladium on charcoal gave rise to the c...
Addition of allyl or vinyl organometallic reagents to chiral a,b- or b,g-unsaturated acylsilanes aff...
The formation of bis(silyl)ketenes on reaction of 2,3-dihydrofuran (and 2,3-dihydro-2-phenylfuran) w...
Part One. Tetraalkylsilanes undergo redistribution reactions quite selectively in the presence of tr...
Thermal rearrangement of the 1,2-bis(silylene), [{(4-ButPh)C(NDip)2}Si−]2 (Dip = 2,6-diisopropylphen...
Thermal rearrangement of the 1,2-bis(silylene), [{(4-ButPh)C(NDip)2}Si-]2 (Dip = 2,6-diisopropylphen...
(C\(_6\)H\(_5\))\(_2\)Si(H)CH\(_2\)X (1 a: X = Cl; 1 b: X = I) und C\(_6\)H\(_5\)(CH\(_3\))Si(H)CH\(...
A new in situ preparation of trimethylsilyl trifluoromethanesulfonate (3) is described: 3 is generat...
An account of the cleavage of the silicon-carbon bond is given and relevant published work is review...
The installation of structural complex oligosilanes from linear starting materials by Lewis acid ind...
Ab initio calculations at the CCSD(T)/6-311++G(2d,p)//B3LYP/6-311++G(d,p) level of theory have been ...
The synthesis and the thermal behaviour of the (methylphenylsilyl)methyl carbonates \(CH_3(C_6H_5)Si...
A mechanism for the homogeneous gas-phase decomposition of SiHCl3, SiH2Cl2, and SiH3Cl in hydrogen i...
Twenty silanes of the type R\(^1\)R\(^2\)Si(H)CH\(_2\)OR\(^3\) (A) were syn- and entropy of activati...
It is well known that silicon undergoes facile 1,5-migrations from carbon to carbon. In an attempt t...
The treatment of alkoxymethyl-substituted hydrosilanes with palladium on charcoal gave rise to the c...
Addition of allyl or vinyl organometallic reagents to chiral a,b- or b,g-unsaturated acylsilanes aff...
The formation of bis(silyl)ketenes on reaction of 2,3-dihydrofuran (and 2,3-dihydro-2-phenylfuran) w...
Part One. Tetraalkylsilanes undergo redistribution reactions quite selectively in the presence of tr...
Thermal rearrangement of the 1,2-bis(silylene), [{(4-ButPh)C(NDip)2}Si−]2 (Dip = 2,6-diisopropylphen...
Thermal rearrangement of the 1,2-bis(silylene), [{(4-ButPh)C(NDip)2}Si-]2 (Dip = 2,6-diisopropylphen...
(C\(_6\)H\(_5\))\(_2\)Si(H)CH\(_2\)X (1 a: X = Cl; 1 b: X = I) und C\(_6\)H\(_5\)(CH\(_3\))Si(H)CH\(...
A new in situ preparation of trimethylsilyl trifluoromethanesulfonate (3) is described: 3 is generat...
An account of the cleavage of the silicon-carbon bond is given and relevant published work is review...
The installation of structural complex oligosilanes from linear starting materials by Lewis acid ind...
Ab initio calculations at the CCSD(T)/6-311++G(2d,p)//B3LYP/6-311++G(d,p) level of theory have been ...
The synthesis and the thermal behaviour of the (methylphenylsilyl)methyl carbonates \(CH_3(C_6H_5)Si...
A mechanism for the homogeneous gas-phase decomposition of SiHCl3, SiH2Cl2, and SiH3Cl in hydrogen i...