The synthesis of the (hydroxymethyl)diorganylsilanes R\(^1\)R\(^2\)Si(H)CH\(_2\)OH (4a: R\(^1\) = R\(^2\) = CH\(_3\), 2-silaisobutanol; 4b: R\(^1\) = CH\(_3\), R\(^2\) == C\(_6\)H\(_5\); 4c: R\(^1\) == R\(^2\) = C\(_6\)H\(_5\))is achieved bythereactionof R\(^1\)R\(^2\)Si(Cl)CH\(_2\)Cl (2a-c) with AcOH/NEt\(_3\) to R\(^1\)R\(^2\)Si(OAc)CH\(_2\)OAc (Ja-c), followed by treating with LiAlH\(_4\) and hydrolysis
International audienceThe replacement of polar O-H bonds in alcohols and phenols with the O-Si linka...
The synthesis of drugs and natural products in enartiomerically pure form is a growing area of resea...
ABSTRACT: The use of Karstedt’s catalyst to study the reduction of Me2NCHO (DMF) by the popular “dua...
Die erstmalige Synthese der (Thioacetoxy-S-methyl)diorganylsilane (CH\(_3\))\(_2\)Si(H)CH\(_2\)SC(O)...
Alkoxysilanes is the unique class of organosilicon compounds that have various fields of the applica...
The 2,2,5,5-tetraorganyl-1,4-dioxa-2,5-disilacyclohexanes 2a-2c were prepared by condensation of the...
Alkoxy(aminoalkyl)silanes are important precursors for the formation of amino-functionalized polysil...
The purpose of the work: the development of methods of the synthesis of 1-organylsylatranes and 1,3-...
The formation of siloxymethylamine intermediates R3SiOCH 2NMe2, 1, as initial products of the reduct...
Jutzi P, Schneider M, Stammler H-G, Neumann B. Synthesis, derivatization, and structure of the silan...
A general method for the formation of acetals using chlorotrimethylsilane has been developed. Dioxol...
A series of unsymmetrically substituted oligosilanes were synthesized via stepwise introduction of d...
The commercially practiced conversion of trimethoxymethylsilane (MTM) to [OSi(OMe)Me)]<sub><i>n</i...
Twenty silanes of the type R\(^1\)R\(^2\)Si(H)CH\(_2\)OR\(^3\) (A) were syn- and entropy of activati...
The review summarizes studies on the «direct synthesis» of alkoxysilanes. Their properties and areas...
International audienceThe replacement of polar O-H bonds in alcohols and phenols with the O-Si linka...
The synthesis of drugs and natural products in enartiomerically pure form is a growing area of resea...
ABSTRACT: The use of Karstedt’s catalyst to study the reduction of Me2NCHO (DMF) by the popular “dua...
Die erstmalige Synthese der (Thioacetoxy-S-methyl)diorganylsilane (CH\(_3\))\(_2\)Si(H)CH\(_2\)SC(O)...
Alkoxysilanes is the unique class of organosilicon compounds that have various fields of the applica...
The 2,2,5,5-tetraorganyl-1,4-dioxa-2,5-disilacyclohexanes 2a-2c were prepared by condensation of the...
Alkoxy(aminoalkyl)silanes are important precursors for the formation of amino-functionalized polysil...
The purpose of the work: the development of methods of the synthesis of 1-organylsylatranes and 1,3-...
The formation of siloxymethylamine intermediates R3SiOCH 2NMe2, 1, as initial products of the reduct...
Jutzi P, Schneider M, Stammler H-G, Neumann B. Synthesis, derivatization, and structure of the silan...
A general method for the formation of acetals using chlorotrimethylsilane has been developed. Dioxol...
A series of unsymmetrically substituted oligosilanes were synthesized via stepwise introduction of d...
The commercially practiced conversion of trimethoxymethylsilane (MTM) to [OSi(OMe)Me)]<sub><i>n</i...
Twenty silanes of the type R\(^1\)R\(^2\)Si(H)CH\(_2\)OR\(^3\) (A) were syn- and entropy of activati...
The review summarizes studies on the «direct synthesis» of alkoxysilanes. Their properties and areas...
International audienceThe replacement of polar O-H bonds in alcohols and phenols with the O-Si linka...
The synthesis of drugs and natural products in enartiomerically pure form is a growing area of resea...
ABSTRACT: The use of Karstedt’s catalyst to study the reduction of Me2NCHO (DMF) by the popular “dua...