Water Oxidation Catalyzed by a New Tetracobalt-Substituted Polyoxometalate Complex: [{Co4(µ-OH)(H2O)3}(Si2W19O70)]11
- Zhu, G.
- Geletii, Y.V.
- Kögerler, P.
- Schilder, H.
- Song, J.
- Lense, S.
- Zhao, C.
- Hardcastle, K.I.
- Musaev, D.G.
- Hill, C.L.
DOI Publisher
Royal Society of Chemistry (RSC)Abstract
A new polyoxometalate of earth adundant elements [{Co(4)(μ-OH)(H(2)O)(3)}(Si(2)W(19)O(70))](11-) has been synthesized, characterized and shown to be a water oxidation catalyst. The initial catalytic complex is unstable and slowly undergoes hydrolysis. The hydrolysis products have been isolated and characterized, and their catalytic water oxidation activity is assessed
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