In the present paper a subclass of scalar Nevanlinna functions is studied, which coincides with the class of Weyl functions associated to a nonnegative symmetric operator of defect one in a Hilbert space. This class consists of all Nevanlinna functions that are holomorphic on (−∞, 0) and all those Nevanlinna functions that have one negative pole a and are injective on (−∞,a)∪(a,0) . These functions are characterized via integral representations and special attention is paid to linear fractional transformations which arise in extension and spectral problems of symmetric and selfadjoint operators.This is an open access article distributed under the terms of the Creative Commons Attribution Noncommercial License (https://creativecommons.org/li...