The enantioselective phospha-Mannich reaction of diethyl phosphite to unactivated N-DPP-protected ketimines catalyzed by a bifunctional iminophosphorane (BIMP) superbase organocatalyst is described. The reaction is applicable to ketimines bearing electron-rich and electron-poor aryl substituents and occurs with excellent yields and moderate enantioselectivities under mild reaction conditions
This thesis presents the development and application of bifunctional iminophosphorane (BIMP) organoc...
Optically active alpha,beta-diaminophosphonic acid derivatives were obtained from the catalytic enan...
Abstract A phosphoiminoBINOL ligand was designed to form a dinuclear metal complex that could hold a...
The enantioselective phospha-Mannich reaction of diethyl phosphite to unactivated N-DPP-protected ke...
An immobilized chiral bifunctional iminophosphorane superbase organocatalyst has been developed and ...
The design, synthesis, and development of a new class of modular, strongly basic, and tunable bifunc...
ABSTRACT: The design, synthesis, and development of a new class of modular, strongly basic, and tuna...
An immobilized chiral bifunctional iminophosphorane superbase organocatalyst has been developed and ...
The design, synthesis, and development of a new class of modular, strongly basic, and tunable bifunc...
The highly diastereo- and enantioselective Mannich addition/cyclisation reaction of α-substituted is...
This thesis describes the development and application of catalytic enantioselective additions to im...
A catalytic asymmetric synthesis of imidazolines with a fully substituted β-carbon atom by a Mannich...
A combination of an amino acid derived chiral phosphine catalyst and methyl acrylate efficiently cat...
This thesis describes the development and application of a new class of bifunctional organocatalysts...
Chapter 1 introduces enantioselective organocatalysis with a specific focus on bifunctional catalyst...
This thesis presents the development and application of bifunctional iminophosphorane (BIMP) organoc...
Optically active alpha,beta-diaminophosphonic acid derivatives were obtained from the catalytic enan...
Abstract A phosphoiminoBINOL ligand was designed to form a dinuclear metal complex that could hold a...
The enantioselective phospha-Mannich reaction of diethyl phosphite to unactivated N-DPP-protected ke...
An immobilized chiral bifunctional iminophosphorane superbase organocatalyst has been developed and ...
The design, synthesis, and development of a new class of modular, strongly basic, and tunable bifunc...
ABSTRACT: The design, synthesis, and development of a new class of modular, strongly basic, and tuna...
An immobilized chiral bifunctional iminophosphorane superbase organocatalyst has been developed and ...
The design, synthesis, and development of a new class of modular, strongly basic, and tunable bifunc...
The highly diastereo- and enantioselective Mannich addition/cyclisation reaction of α-substituted is...
This thesis describes the development and application of catalytic enantioselective additions to im...
A catalytic asymmetric synthesis of imidazolines with a fully substituted β-carbon atom by a Mannich...
A combination of an amino acid derived chiral phosphine catalyst and methyl acrylate efficiently cat...
This thesis describes the development and application of a new class of bifunctional organocatalysts...
Chapter 1 introduces enantioselective organocatalysis with a specific focus on bifunctional catalyst...
This thesis presents the development and application of bifunctional iminophosphorane (BIMP) organoc...
Optically active alpha,beta-diaminophosphonic acid derivatives were obtained from the catalytic enan...
Abstract A phosphoiminoBINOL ligand was designed to form a dinuclear metal complex that could hold a...