The ytterbium 1,4-benzenedicarboxylate (BDC) framework [Yb2(BDC)3(DMF)2]·H2O (1) crystallises from a N,N-dimethylformamide (DMF)-rich solution at 80–120 °C. (1) is constructed from infinite chains of dicarboxylate-bridged seven-coordinate Yb atoms, cross-linked in two directions by BDC to yield diamond-shaped channels (sra topology) lined by coordinated DMF molecules and occluded water. Increasing the water content in the synthesis solution yields a material with more crystal water Yb2(BDC)3(DMF)2(H2O)2 (2), in which the Yb centres are eight-coordinate and form dimers bridged by BDC to give two interpenetrating networks of pcu (α-Po) topology. Upon extended reaction in this water-rich solvent mixture, an alternative phase is formed: an anhy...
The fact that asymmetrically substituted dicarboxylate is capable of forming two different coordinat...
The ligand 2,6,2′,6′-tetranitro-biphenyl-4,4′-dicarboxylic acid (<b>H</b><sub><b>2</b></sub><b>L</b>...
In this work, we report the synthesis, structural characterisation and sorption properties of an 8-f...
The ytterbium 1,4-benzenedicarboxylate (BDC) framework [Yb2(BDC)3(DMF)2]andmiddot;H2O (1) crystallis...
Using time-resolved monochromatic high energy X-ray diffraction, we present an in situ study of the ...
Using time-resolved monochromatic high energy X-ray diffraction, we present an in situ study of the ...
Depending on the solvothermal reaction conditions, we obtained three different metal‐organic framewo...
We report a study of the solvothermal formation of the interpenetrated form of the zinc 1,4-benzene ...
Understanding the driving forces controlling crystallisation has important consequences ranging ...
Understanding the driving forces controlling crystallization is essential for the efficient synthesi...
We report for the first time the complete and reversible exchange of metal ions constituting a robus...
Since the discovery of MOFs in the 1990s, research into these materials has grown at an exceptional ...
Ca(BDC)(DMF)(H<sub>2</sub>O) with square lattice topology (sql) and rhombic-shaped channels cryst...
Metal-organic frameworks (MOFs)—network structures built from metal ions or clusters and connecting ...
In situ energy-dispersive X-ray diffraction has been used to investigate the synthesis of the recent...
The fact that asymmetrically substituted dicarboxylate is capable of forming two different coordinat...
The ligand 2,6,2′,6′-tetranitro-biphenyl-4,4′-dicarboxylic acid (<b>H</b><sub><b>2</b></sub><b>L</b>...
In this work, we report the synthesis, structural characterisation and sorption properties of an 8-f...
The ytterbium 1,4-benzenedicarboxylate (BDC) framework [Yb2(BDC)3(DMF)2]andmiddot;H2O (1) crystallis...
Using time-resolved monochromatic high energy X-ray diffraction, we present an in situ study of the ...
Using time-resolved monochromatic high energy X-ray diffraction, we present an in situ study of the ...
Depending on the solvothermal reaction conditions, we obtained three different metal‐organic framewo...
We report a study of the solvothermal formation of the interpenetrated form of the zinc 1,4-benzene ...
Understanding the driving forces controlling crystallisation has important consequences ranging ...
Understanding the driving forces controlling crystallization is essential for the efficient synthesi...
We report for the first time the complete and reversible exchange of metal ions constituting a robus...
Since the discovery of MOFs in the 1990s, research into these materials has grown at an exceptional ...
Ca(BDC)(DMF)(H<sub>2</sub>O) with square lattice topology (sql) and rhombic-shaped channels cryst...
Metal-organic frameworks (MOFs)—network structures built from metal ions or clusters and connecting ...
In situ energy-dispersive X-ray diffraction has been used to investigate the synthesis of the recent...
The fact that asymmetrically substituted dicarboxylate is capable of forming two different coordinat...
The ligand 2,6,2′,6′-tetranitro-biphenyl-4,4′-dicarboxylic acid (<b>H</b><sub><b>2</b></sub><b>L</b>...
In this work, we report the synthesis, structural characterisation and sorption properties of an 8-f...