Addition of H2 to the precursor [Rh(Cyp2P(CH2)2PCyp2)(η2 :η2 -C7H8)][BArF 4] gives the σ-alkane complex [Rh(Cyp2P(CH2)2PCyp2)(η2 :η2 -C7H12)][BArF 4] by a single-crystal to single–crystal reaction, as characterized by X-ray crystallography, SSNMR spectroscopy and periodic DFT. An unexpected rearrangement of the {Rh(L2)}+ fragment is revealed
The controlled catalytic functionalization of alkanes via the activation of C–H bonds is a significa...
Single-crystal to single-crystal solid/gas reactivity and catalysis starting from the precursor sigm...
Single-crystal to single-crystal solid/gas reactivity and catalysis starting from the precursor sigm...
Addition of H2 to the precursor [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H8)][BArF4] gives the σ-alkane complex...
Addition of H<sub>2</sub> to the precursor [Rh(Cyp<sub>2</sub>PCH<sub>2</sub>CH<sub>2</sub>PCyp<su...
Addition of H2 to the precursor [Rh(Cyp2PCH2CH2PCyp2)(η2:η2- C7H8)][BArF 4] gives the σ-alkane compl...
The pentane σ-complex [Rh{Cy2P(CH2CH2)PCy2}(η2:η2-C5H12)][BArF4] is synthesized by a solid/gas singl...
The pentane σ–complex [Rh{Cy2P(CH2CH2)PCy2}(η2:η2–C5H12)][BArF4] is synthesized by a solid/gas sing...
The pentane σ-complex [Rh{Cy2 P(CH2 CH2 )PCy2 }(η(2) :η(2) -C5 H12 )][BAr(F) 4 ] is synthesized by a...
The sequential solid/gas single-crystal to single-crystal reaction of [Rh(Cy2P(CH2)3PCy2)(COD)][BArF...
The use of solid/gas and single-crystal to single-crystal synthetic routes is reported for the synth...
Using solid-state molecular organometallic (SMOM) techniques, in particular solid/gas single-crystal...
The use of solid/gas and single-crystal to single-crystal synthetic routes is reported for the synth...
A review of computational studies on the structures, bonding and reactivity of rhodium σ-alkane comp...
The controlled catalytic functionalization of alkanes via the activation of C-H bonds is a significa...
The controlled catalytic functionalization of alkanes via the activation of C–H bonds is a significa...
Single-crystal to single-crystal solid/gas reactivity and catalysis starting from the precursor sigm...
Single-crystal to single-crystal solid/gas reactivity and catalysis starting from the precursor sigm...
Addition of H2 to the precursor [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H8)][BArF4] gives the σ-alkane complex...
Addition of H<sub>2</sub> to the precursor [Rh(Cyp<sub>2</sub>PCH<sub>2</sub>CH<sub>2</sub>PCyp<su...
Addition of H2 to the precursor [Rh(Cyp2PCH2CH2PCyp2)(η2:η2- C7H8)][BArF 4] gives the σ-alkane compl...
The pentane σ-complex [Rh{Cy2P(CH2CH2)PCy2}(η2:η2-C5H12)][BArF4] is synthesized by a solid/gas singl...
The pentane σ–complex [Rh{Cy2P(CH2CH2)PCy2}(η2:η2–C5H12)][BArF4] is synthesized by a solid/gas sing...
The pentane σ-complex [Rh{Cy2 P(CH2 CH2 )PCy2 }(η(2) :η(2) -C5 H12 )][BAr(F) 4 ] is synthesized by a...
The sequential solid/gas single-crystal to single-crystal reaction of [Rh(Cy2P(CH2)3PCy2)(COD)][BArF...
The use of solid/gas and single-crystal to single-crystal synthetic routes is reported for the synth...
Using solid-state molecular organometallic (SMOM) techniques, in particular solid/gas single-crystal...
The use of solid/gas and single-crystal to single-crystal synthetic routes is reported for the synth...
A review of computational studies on the structures, bonding and reactivity of rhodium σ-alkane comp...
The controlled catalytic functionalization of alkanes via the activation of C-H bonds is a significa...
The controlled catalytic functionalization of alkanes via the activation of C–H bonds is a significa...
Single-crystal to single-crystal solid/gas reactivity and catalysis starting from the precursor sigm...
Single-crystal to single-crystal solid/gas reactivity and catalysis starting from the precursor sigm...