D-optimal mixture design for the optimization of extraction induced by emulsion breaking for multielemental determination in edible vegetable oils by microwave-induced plasma optical emission spectrometry

A sample pretreatment based on an extraction process by emulsion breaking for multi-element determination in edible oils was developed. The determination of eight trace elements (Al, Ba, Cu, Cr, P, Ni, Ti, and Zn) was carried out by microwave-induced plasma optical emission spectrometry (MIP OES) after the extraction procedure. A D-optimal mixture experimental design was used to obtain the best experimental conditions for the extraction induced by emulsion breaking (EIEB). The proportion of HNO3 solution, Triton X-100 solution and sample was evaluated in a multivariate manner. The best recovery efficiency was obtained with 1.0 mL of 30% (v/v) HNO3, 1.0 mL of 30% (w/v) Triton-X 100 and 3.0 mL of the sample. The precisions, established as the relative standard deviation (RSD, %), were better than 2.5% for all analytes. The developed method was applied to the analysis of commercial vegetable oils with low limits of detection and good precision.Fil: Carneiro, Angélica Fagundes. Universidade Federal do Recôncavo da Bahia; BrasilFil: Carneiro, Candice Nóbrega. Universidade Federal do Recôncavo da Bahia; BrasilFil: Pires, Laís de N.. Universidade Federal da Bahia; BrasilFil: Teixeira, Leonardo S. G.. Universidade Federal da Bahia; BrasilFil: Azcarate, Silvana Mariela. Universidad Nacional de La Pampa. Facultad de Ciencias Exactas y Naturales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Ciencias de la Tierra y Ambientales de La Pampa. Universidad Nacional de La Pampa. Facultad de Ciencias Exactas y Naturales. Instituto de Ciencias de la Tierra y Ambientales de La Pampa; ArgentinaFil: Dias, Fabio de Sousa. Universidade Federal da Bahia; Brasi