Cost-effective routes for catalytic biomass upgrading

Catalytic hydrodeoxygenation (HDO) is a fundamental and promising route for bio-oil upgrading to produce petroleum-like hydrocarbon fuels or chemical building blocks. One of the main challenges of this technology is the demand of high-pressure H, which poses high costs and safety concerns. Accordingly, developing cost-effective routes for biomass or bio-oil upgrading without the supply of commercial H is essential to implement the HDO at commercial scale. This article critically reviewed the very recent studies relating to the novel strategies for upgrading the biofeedstocks with ‘green’ H generated from renewable sources. More precisely, catalytic transfer hydrogenation/hydrogenolysis, combined reforming and HDO, combined metal hydrolysis and HDO, water-assisted in-situ HDO and nonthermal plasma technology and self-supported hydrogenolysis are reviewed herein. Current challenges and research trends of each strategy are also proposed aiming to motivate further improvement of these novel routes to become competitive alternatives to conventional HDO technology