We show that state-of-the-art tube models overestimate the influence of contour length fluctuations (CLF) on the apparent plateau modulus of entangled flexible polymers. The observed inconsistency between the molecular weight dependence of the relaxation time and plateau modulus questions some of the underlying physics and suggests, in particular, that the CLF-based explanation for the zero-shear viscosity vs molecular weight scaling law is not entirely satisfactory
We investigate the nonequilibrium tube length fluctuations during the relaxation of an initially str...
cited By 67International audienceThe viscoelasticity of unentangled polystyrene melts has been inves...
Although the tube theory is successful in describing entangled polymers qualitatively, a more quanti...
We show that state-of-the-art tube models overestimate the influence of contour length fluctuations ...
ABSTRACT: We show that state-of-the-art tube models overestimate the influence of contour length flu...
Tube models have achieved spectacular success for predictions of the linear rheology of entangled po...
Recently, Liu et al. (Macromolecules 2006, 39, 3093) showed a systematic discrepancy of tube model p...
By studying the relaxation of small amounts of short entangled "probe" chains in a high molecular we...
We revisit the nonuniversal aspect of polymer dynamics by considering both new and existing data on ...
Tube models derived from the basic ideas of De Gennes and Doi & Edwards on reptation of entangled ch...
We revisit the nonuniversal aspect of polymer dynamics by considering both new and existing data on ...
\u3cp\u3eThe aim of the present paper is to analyse the differences between tube-based models which ...
The aim of the present paper is to analyse the differences between tube-based models which are widel...
It is well-known that the packing model (Fetters and co-workers) shows the relationship between micr...
We study the interaction between constraint release and contour length fluctuations in well entangle...
We investigate the nonequilibrium tube length fluctuations during the relaxation of an initially str...
cited By 67International audienceThe viscoelasticity of unentangled polystyrene melts has been inves...
Although the tube theory is successful in describing entangled polymers qualitatively, a more quanti...
We show that state-of-the-art tube models overestimate the influence of contour length fluctuations ...
ABSTRACT: We show that state-of-the-art tube models overestimate the influence of contour length flu...
Tube models have achieved spectacular success for predictions of the linear rheology of entangled po...
Recently, Liu et al. (Macromolecules 2006, 39, 3093) showed a systematic discrepancy of tube model p...
By studying the relaxation of small amounts of short entangled "probe" chains in a high molecular we...
We revisit the nonuniversal aspect of polymer dynamics by considering both new and existing data on ...
Tube models derived from the basic ideas of De Gennes and Doi & Edwards on reptation of entangled ch...
We revisit the nonuniversal aspect of polymer dynamics by considering both new and existing data on ...
\u3cp\u3eThe aim of the present paper is to analyse the differences between tube-based models which ...
The aim of the present paper is to analyse the differences between tube-based models which are widel...
It is well-known that the packing model (Fetters and co-workers) shows the relationship between micr...
We study the interaction between constraint release and contour length fluctuations in well entangle...
We investigate the nonequilibrium tube length fluctuations during the relaxation of an initially str...
cited By 67International audienceThe viscoelasticity of unentangled polystyrene melts has been inves...
Although the tube theory is successful in describing entangled polymers qualitatively, a more quanti...