Enabling the Li-ion conductivity of Li-metal fluorosulphates by ionic liquid grafting

Recently unveiled 'alkali metal fluorosulphate (AMSO 4F)' class of compounds offers promising electrochemical and transport properties. Registering conductivity value as high as 10 -7 S cm -1 in NaMSO 4F phases, we explored the fluorosulphate group to design novel compounds with high Li-ion conductivity suitable for solid electrolyte applications. In the process, we produced sillimanite-structured LiZnSO 4F by low temperature synthesis (T ≤ 300 °C). Examining this phase, we accidentally discovered the possibility of improving the ionic conductivity of poor conductors by forming a monolayer of ionic liquid at their particle surface. This phenomenon was studied by solid-state NMR, XPS and AC impedance spectroscopy techniques. Further, similar trends were noticed in other fluorosulphate materials like tavorite LiCoSO 4F and triplite LiMnSO 4F. With this study, we propose 'ionic liquid grafting' as an interfacial route to enable good Li-ion conductivity in otherwise poor conducting ceramics