Unexpected formation of (dimethylaminomethylene)methylamide complexes from the reactions between metal chlorides and lithium dimethylamide

Zhang, Xin-Hao
Chen, Shu-Jian
Cai, Hu
Im, Hee-Jung
Chen, Tianniu
Yu, Xianghua
Chen, Xuetai
Lin, Zhenyang
Wu, Yun-Dong
Xue, Zi-Ling

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Publication date

January 2008

DOI

10.1021/om701173m

ISSN

0276-7333

Journal

0276-7333

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Abstract

Reactions of MCl5 (M = Nb, Ta) with LiNMe2 have been found to yield M(NMe2)(4)(eta(2)-MeNCH2NMe2) (M = Nb, 2a; Ta, 2b) containing a chelating ligand (dimethylaminomethylene)methylamide, as confirmed by NMR spectroscopy, DFT calculations, and their reactivity studies

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Unexpected formation of (dimethylaminomethylene)methylamide complexes from the reactions between metal chlorides and lithium dimethylamide

Abstract

Extracted data

Unexpected formation of (dimethylaminomethylene)methylamide complexes from the reactions between metal chlorides and lithium dimethylamide

Abstract

Extracted data

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