Kinetic data are presented for the reaction of alkylchromium complexes (H2O)([14]aneN(4))CrR2+ ([14]aneN(4) = 1,4,8,11-tetraazacyclotetradecane) with Hg2+ via electrophilic substitution. The rate constants decrease in the order CH3 (1.1 x 10(6) mol(-1) dm(3) s(-1)) > C2H5 (7.7 x 10(2)) > C3H7 (59) > 2-C3H7 (0.12) > CH2C(CH3)(3) (0.0086). A series of meta and para substituted benzyl complexes obey a Hammett relationship with the reaction constant rho = -1.66, consistent with electrophilic substitution at alpha -carbon
The review provides insight into the mechanism of ligand substitution and electron transfer (from ch...
The H+- and Cl--assisted dissociation kinetics and the stabilities of the complexes [Hg(sar)](2+) an...
Reactive species like high-valent metal-oxo complexes and carbon and oxygen centered radicals are im...
Kinetic data are presented for the reaction of alkylchromium complexes (H2O)([14]aneN4)CrR2+ ([14]an...
Kinetic data are presented for the reaction of alkylchromium complexes (H2O)([14]aneN4)CrR2+ ([14]an...
Reaction pathways leading to the formation and cleavage of a transition metal-carbon bond at various...
AbstractStopped flow spectrophotometry was used to study the complexation kinetics of the N-pendant ...
Anet was the first to isolate a stable sigma bonded organochromium (III) complex.1 This was the ben...
Three projects were carried out, each dealing with the kinetics and mechanism of reactions of sigma-...
AbstractStopped flow spectrophotometry was used to study the complexation kinetics of the N-pendant ...
The kinetics of the reactions between tetra-alkyltins, R4Sn, (R = Me, Et) and mercury(II) halides, H...
The review provides insight into the mechanism of ligand substitution and electron transfer (from ch...
The review provides insight into the mechanism of ligand substitution and electron transfer (from ch...
The kinetics of the reactions between tetra-alkyltins, R4Sn, (R = Me, Et) and mercury(II) halides, H...
The review provides insight into the mechanism of ligand substitution and electron transfer (from ch...
The review provides insight into the mechanism of ligand substitution and electron transfer (from ch...
The H+- and Cl--assisted dissociation kinetics and the stabilities of the complexes [Hg(sar)](2+) an...
Reactive species like high-valent metal-oxo complexes and carbon and oxygen centered radicals are im...
Kinetic data are presented for the reaction of alkylchromium complexes (H2O)([14]aneN4)CrR2+ ([14]an...
Kinetic data are presented for the reaction of alkylchromium complexes (H2O)([14]aneN4)CrR2+ ([14]an...
Reaction pathways leading to the formation and cleavage of a transition metal-carbon bond at various...
AbstractStopped flow spectrophotometry was used to study the complexation kinetics of the N-pendant ...
Anet was the first to isolate a stable sigma bonded organochromium (III) complex.1 This was the ben...
Three projects were carried out, each dealing with the kinetics and mechanism of reactions of sigma-...
AbstractStopped flow spectrophotometry was used to study the complexation kinetics of the N-pendant ...
The kinetics of the reactions between tetra-alkyltins, R4Sn, (R = Me, Et) and mercury(II) halides, H...
The review provides insight into the mechanism of ligand substitution and electron transfer (from ch...
The review provides insight into the mechanism of ligand substitution and electron transfer (from ch...
The kinetics of the reactions between tetra-alkyltins, R4Sn, (R = Me, Et) and mercury(II) halides, H...
The review provides insight into the mechanism of ligand substitution and electron transfer (from ch...
The review provides insight into the mechanism of ligand substitution and electron transfer (from ch...
The H+- and Cl--assisted dissociation kinetics and the stabilities of the complexes [Hg(sar)](2+) an...
Reactive species like high-valent metal-oxo complexes and carbon and oxygen centered radicals are im...
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