Enhancing Chromium (VI) removal from synthetic and real tannery effluents by using diatomite-embedded nanopyroxene

A commercial filter aid material of Diatomite was modified via loading it with a low mass fraction of polyethylenimine-functionalized pyroxene nanoparticles (PEI-PNs) to enhance its adsorption activities. The modified Diatomite was then used for Cr(VI) removal from dichromate solution and from real tannery wastewater. For the synthetic wastewater, batch adsorption experiments were first performed at various pH and Cr(VI) initial concentrations. Then, the obtained kinetic parameters were used to investigate the continuous adsorption inside the fixed-bed column. The continuous removal of the Cr(VI) was performed inside a fixed-bed column under various influent flow rates, Cr(VI) initial concentrations, and bed-heights. In the column experiments, high adsorption of Cr(VI) was observed at low flow rates, high bed heights, and low influent initial concentrations. A dimensionless form of the advection-axial dispersion model, featuring Peclet number as a fitting parameter, was then used to study the breakthrough behavior under various dynamic parameters. Afterward, the modified Diatomite was used to remediate well characterized real tannery wastewater. For the treatment of the tannery wastewater, our modified filter aid, compared with the non-modified one, showed an outstanding performance and a higher removal efficiency.The authors are grateful to the Natural Sciences and Engineering Research Council of Canada (NSERC) (Grant No. RGPIN-2015- 05222). A special acknowledgement to Dr. Tobias Fürstenhaupt for access to the Microscopy and Imaging Facility of the Health Science Center at the University of Calgary and Dr. Christopher Debuhr for providing access to the Instrumentation Facility for Analytical Electron Microscopy at the University of Calgary and Dr. Gerardo Vitale for drawing the CPK representation of nanopyroxene and diatomite surface