The response of pure organic crystals to ionising radiations

The introduction contains introductory remarks on scintillation counters together with a brief description of the exciton theory believed to be the means of primary energy migration within organic crystals. Part I contains a review of the data published on the reletive responses of different organic crystals and the attempted correlations of these results with the molecular structures of the different phosphors. From data which may be accepted as being both reliable and suitable for comparison it is concluded that theories involving correlations between phosphor efficiencies and molecular structures may be tested only if the efficiency data has (i) been extrapolated to give results for crystals of very small thickness and {ii) been obtained at very low temperatures. Part II contains accurate calculations based on the exciton theory proposed by Birks (1951 ) to account for the response of crystals to different types of ionising radiations. Satisfactory agreement is obta1ned with all the avalable experimental data in the literature. In part III an account is given of the response of organic crystals observed by the author for low-energy ⋉particles, and of the similar behaviour found by Taylor et al, (1951 ) for low-energy electrons. A possible extension of the theory described in part II, allowing for the escape of excitons through the crystal surface is given accounting for this behaviour. An exciton mean free path in anthracene, terphenyl and stilbene of about 3 - 7/u is obtained. Results were obtained with strong ⋉-particle sources which could not be explained. in terms ot normal response of the phosphor used. This effect was inventigatea as described in part IV, and it is shown that photons are produced in air, glass and quartz when these materials are irradiated by ⋉particles. This luminescence was probably responsible for the "scintillations" which Richards and Cole (1951) have ascribed to thin films of various materials. Problems requiring further investigation are indicated