POSS Fillers as a Factor Influencing on Viscoelastic Properties, Crystallization, and Thermo-Oxidative Degradation of Poly(Lactic Acid)-Epoxidized Natural Rubber PLA/ENR Blend

Polyhedral oligomeric silsesquioxanes (POSS) can be considered as the smallest silica particles that contain an inorganic cage-like silicon-oxygen structure surrounded by organic substituents. POSS are known to be reinforcing fillers able to enhance the fire retardancy and to increase the thermo-oxidative stability. The application of POSS with various functional groups and their effect on the properties of poly(lactic acid) (PLA) is analyzed based on the literature review. The influence of POSS with hydroxyl and glycidyl groups on the viscoelastic properties, crystallization, and thermo-oxidative degradation of PLA containing various contents of natural rubber ENR is discussed. The application of POSS with hydroxyl and glycidyl groups as an additive enhancing compatibility of PLA toughened by epoxidized rubber (ENR) is described. It is reported that POSS molecules with hydroxyl groups can enhance the thermo-oxidative stability of PLA melt