The adsorption of poly(ethylene oxide), PEO, from dilute solutions in 1 mM aqueous NaCl to germanium at 30°C, was investigated by polarized infrared spectroscopy in attenuated total internal reflection (ATR). PEO aggregation could be prevented with careful sample preparation. After adsorption, chain anisotropy was deduced from the COC stretching vibrations along the polymer backbone and found to indicate substantial backbone alignment parallel to the surface
We measure, for the first time, the separate surface coverage-dependent orientations of trains and o...
Stretched polyethylene (PE) films have been used to orient small molecules for decades by depositing...
The literature lacks established concrete parameters for assigning grafted chain regimes. In this co...
The adsorption of poly(ethylene oxide), PEG, from dilute solutions in 1 mM aqueous NaCl to germanium...
The influence of shear flow of solvent past poly(methyl methacrylate) chains adsorbed onto germanium...
ABSTRACT: We examine the distribution of adsorption substates, in contrast to their average. The dis...
We examine the distribution of adsorption substates, in contrast to their average. The distribution ...
Physical property studies of surfaces formed by chemisorption of polyethylene oxide (PEO) onto gold ...
The method of infrared spectroscopy in attenuated total reflection (IR-ATR) has been used to study k...
The adsorption of graft copolymers of poly(acrylamide) (PAAm, backbone) and poly(ethylene oxide) (PE...
We present a systematic study of how adsorption history affects the thickness, surface forces, and i...
Monolayers of polystyrene-polyethylene oxide (PS-PEO) copolymers at the air-water interface have bee...
We study the time dependent composition and structure of macromolecules physisorbed from solution to...
crystallinity and the level of molecular orientation of the polymer are highest at the film surface ...
Multiarm star copolymers with approximately 460 poly(ethylene oxide) (PEO) arms that have a degree ...
We measure, for the first time, the separate surface coverage-dependent orientations of trains and o...
Stretched polyethylene (PE) films have been used to orient small molecules for decades by depositing...
The literature lacks established concrete parameters for assigning grafted chain regimes. In this co...
The adsorption of poly(ethylene oxide), PEG, from dilute solutions in 1 mM aqueous NaCl to germanium...
The influence of shear flow of solvent past poly(methyl methacrylate) chains adsorbed onto germanium...
ABSTRACT: We examine the distribution of adsorption substates, in contrast to their average. The dis...
We examine the distribution of adsorption substates, in contrast to their average. The distribution ...
Physical property studies of surfaces formed by chemisorption of polyethylene oxide (PEO) onto gold ...
The method of infrared spectroscopy in attenuated total reflection (IR-ATR) has been used to study k...
The adsorption of graft copolymers of poly(acrylamide) (PAAm, backbone) and poly(ethylene oxide) (PE...
We present a systematic study of how adsorption history affects the thickness, surface forces, and i...
Monolayers of polystyrene-polyethylene oxide (PS-PEO) copolymers at the air-water interface have bee...
We study the time dependent composition and structure of macromolecules physisorbed from solution to...
crystallinity and the level of molecular orientation of the polymer are highest at the film surface ...
Multiarm star copolymers with approximately 460 poly(ethylene oxide) (PEO) arms that have a degree ...
We measure, for the first time, the separate surface coverage-dependent orientations of trains and o...
Stretched polyethylene (PE) films have been used to orient small molecules for decades by depositing...
The literature lacks established concrete parameters for assigning grafted chain regimes. In this co...