When models are inaccurate, the performance of model-based control will degrade. For linear quadratic control, an event-triggered learning framework is proposed that automatically detects inaccurate models and triggers the learning of a new process model when needed. This is achieved by analyzing the probability distribution of the linear quadratic cost and designing a learning trigger that leverages Chernoff bounds. In particular, whenever empirically observed cost signals are located outside the derived confidence intervals, we can provably guarantee that this is with high probability due to a model mismatch. With the aid of numerical and hardware experiments, we demonstrate that the proposed bounds are tight and that the event-triggered ...