Add to ORKGInternational audienceThis Concept article highlights recent research on Lewis acid adducts of dinitrogen complexes, including our contributions. After a reminder of the early works, it is demonstrated that such kind of species offers a new platform for dinitrogen functionalization as well as valuable models for the understanding of elementary steps of (bio)catalytic cycles. When possible, parallels regarding this mode of activation from the orbital point of view are drawn between the different systems discussed herein
The theme of this study is reactivity at the ligand and how remote, relative to the metal, activatio...
During recent years, great achievements have been made in the field of organometallic chemistry, for...
Indenyl zirconocene dinitrogen complexes were synthesized from the direct activation of N2 by isolab...
International audienceThis Concept article highlights recent research on Lewis acid adducts of dinit...
International audienceThis article gathers, as of 2020, examples of (hetero)dinuclear dinitrogen com...
The end of the metal age: Recent developments in small-molecule activation and chemical transformati...
Acidic secondary-coordination sphere interactions are critical components of many metalloenzymes tha...
Molecular orbital theory has been used to study a series of [(μ-N 2)-{ML3}2] complexes as models for...
International audienceThe reaction of trans‐[M(N2)2(dppe)2] (M=Mo, 1Mo, M=W, 1W) with B(C6F5)3 (2) p...
Dinuclear dinitrogen complexes have been reported for all transition metals with the exception of Hf...
The synthesis of two new proligands for early metal activation of dinitrogen is reported. The new di...
The N[triple bond, length as m-dash]N triple bond can be cleaved in silico with a light atom molecul...
Computational investigations were carried out to probe the potential of several dicoordinate, singly...
Molecular nitrogen activation and functionalization are among the most important challenge in modern...
Advances in main group chemistry are challenging the status of the transition metals. Small-molecule...
The theme of this study is reactivity at the ligand and how remote, relative to the metal, activatio...
During recent years, great achievements have been made in the field of organometallic chemistry, for...
Indenyl zirconocene dinitrogen complexes were synthesized from the direct activation of N2 by isolab...
International audienceThis Concept article highlights recent research on Lewis acid adducts of dinit...
International audienceThis article gathers, as of 2020, examples of (hetero)dinuclear dinitrogen com...
The end of the metal age: Recent developments in small-molecule activation and chemical transformati...
Acidic secondary-coordination sphere interactions are critical components of many metalloenzymes tha...
Molecular orbital theory has been used to study a series of [(μ-N 2)-{ML3}2] complexes as models for...
International audienceThe reaction of trans‐[M(N2)2(dppe)2] (M=Mo, 1Mo, M=W, 1W) with B(C6F5)3 (2) p...
Dinuclear dinitrogen complexes have been reported for all transition metals with the exception of Hf...
The synthesis of two new proligands for early metal activation of dinitrogen is reported. The new di...
The N[triple bond, length as m-dash]N triple bond can be cleaved in silico with a light atom molecul...
Computational investigations were carried out to probe the potential of several dicoordinate, singly...
Molecular nitrogen activation and functionalization are among the most important challenge in modern...
Advances in main group chemistry are challenging the status of the transition metals. Small-molecule...
The theme of this study is reactivity at the ligand and how remote, relative to the metal, activatio...
During recent years, great achievements have been made in the field of organometallic chemistry, for...
Indenyl zirconocene dinitrogen complexes were synthesized from the direct activation of N2 by isolab...