In this contribution we analyse the influence of adsorption cycling, crystal size, and temperature on the switching behaviour of the flexible Zr-based metal-organic framework DUT-98. We observe a shift in the gate opening pressure upon cycling of adsorption experiments of micro meter-sized crystals and assign this to a fragmentation of the crystals. In a series of modulated syntheses we downsize the average crystal size of DUT-98 crystals from 120 µm to 50 nm and characterize the obtained solids by X-ray diffraction, infrared spectroscopy, as well as scanning and transmission electron microscopy. We analyse the adsorption behaviour by nitrogen and water adsorption at 77 K and 298 K, respectively and show that adsorption-induced flexibility ...
The topic of this thesis is the thermodynamical, mechanical and adsorptive behavior of Soft Porous C...
Water adsorption in porous materials is important for many applications such as dehumidification, th...
International audienceMuch attention has recently been focused on a fascinating subclass of metal‐or...
In this contribution we analyze the influence of adsorption cycling, crystal size, and temperature o...
In this contribution we analyze the influence of adsorption cycling, crystal size, and temperature o...
*S Supporting Information ABSTRACT: Understanding the adsorption of water in metal−organic framework...
Metal-Organic Frameworks (MOFs) are highly porous materials built from inorganic nodes joined by org...
The origin of crystal-size-dependent adsorption behavior of flexible metal-organic frameworks is inc...
ZIF-8 is a flexible zeolitic imidazole-based metal−organic framework whose narrow pore apertures swi...
A chemically and thermally stable MOF with composition Zr 6 O 4 (OH) 4 (tdc) 4 (CH 3 COO) 4 (tdc, 2,...
Текст статьи не публикуется в открытом доступе в соответствии с политикой журнала.Switchable pillare...
Understanding the adsorption of water in metal–organic frameworks (MOF), and particularly in soft po...
The topic of this thesis is the thermodynamical, mechanical and adsorptive behavior of Soft Porous C...
Water adsorption in porous materials is important for many applications such as dehumidification, th...
International audienceMuch attention has recently been focused on a fascinating subclass of metal‐or...
In this contribution we analyze the influence of adsorption cycling, crystal size, and temperature o...
In this contribution we analyze the influence of adsorption cycling, crystal size, and temperature o...
*S Supporting Information ABSTRACT: Understanding the adsorption of water in metal−organic framework...
Metal-Organic Frameworks (MOFs) are highly porous materials built from inorganic nodes joined by org...
The origin of crystal-size-dependent adsorption behavior of flexible metal-organic frameworks is inc...
ZIF-8 is a flexible zeolitic imidazole-based metal−organic framework whose narrow pore apertures swi...
A chemically and thermally stable MOF with composition Zr 6 O 4 (OH) 4 (tdc) 4 (CH 3 COO) 4 (tdc, 2,...
Текст статьи не публикуется в открытом доступе в соответствии с политикой журнала.Switchable pillare...
Understanding the adsorption of water in metal–organic frameworks (MOF), and particularly in soft po...
The topic of this thesis is the thermodynamical, mechanical and adsorptive behavior of Soft Porous C...
Water adsorption in porous materials is important for many applications such as dehumidification, th...
International audienceMuch attention has recently been focused on a fascinating subclass of metal‐or...