Add to ORKGThe analysis of the λ5797.1 diffuse interstellar band (DIB) by Huang & Oka concludes that the carrier is a chain-like molecule with five to seven heavy atoms with a large oscillator strength, f ≈ 1, for the electronic transition. The spectra of carbon chains of this size with transitions in the visible have been obtained in the gas phase, but the f-values are too small. We have now found that certain carbon-chain cations with transitions in the DIB range have large f-values. An example is the origin band at 4387.7 Å of the 1 1AA1 electronic transition of the H2C7H+ chain with f ≈ 0.3. This could be measured in the gas phase at 10 K in an ion trap. Astrophysical relevance of such cations is discussed
Recent low-temperature laboratory measurements and astronomical observations have proved that the fu...
Recent low-temperature laboratory measurements and astronomical observations have proved that the fu...
The gas phase spectrum of the cyclic C18 molecule recorded in the laboratory at a temperature typica...
$^{a}$ H. Linnartz, T. Motylewski and J.P. Maier, J. Chem. Phys., 109, 3819, (1998). $^{b}$ M. Tulej...
The gas-phase electronic spectra of linear OC4O+ and a planar C6H2O+ isomer were obtained at a rotat...
Author Institution: Department of Chemistry, University of Basel, Klingelbergstrasse 80, CH-4056 Bas...
Author Institution: Institute of Physical Chemistry, University of BaselThe electronic spectra of a ...
Author Institution: Department of Chemistry, University of BaselThe carbon chains $C_{n} H (n=2-6)$ ...
Author Institution: Department of Chemistry, University of BaselThe carbon chains $C_{n} H (n=2-6)$ ...
International audienceAbstract Only 4 of the diffuse interstellar bands (DIBs) are currently account...
Measurement of the Π3−Π3 transition of C6H+ in the gas phase near 19486 cm−1 is reported. The experi...
Recent low-temperature laboratory measurements and astronomical observations have proved that the fu...
Our research has focused on the measurement of the electronic spectra of unstable molecules which ar...
Measurement of the 3Π-3Π transition of C6H+ in the gas phase near 19486 cm−1 is reported. The experi...
Recent low-temperature laboratory measurements and astronomical observations have proved that the fu...
Recent low-temperature laboratory measurements and astronomical observations have proved that the fu...
Recent low-temperature laboratory measurements and astronomical observations have proved that the fu...
The gas phase spectrum of the cyclic C18 molecule recorded in the laboratory at a temperature typica...
$^{a}$ H. Linnartz, T. Motylewski and J.P. Maier, J. Chem. Phys., 109, 3819, (1998). $^{b}$ M. Tulej...
The gas-phase electronic spectra of linear OC4O+ and a planar C6H2O+ isomer were obtained at a rotat...
Author Institution: Department of Chemistry, University of Basel, Klingelbergstrasse 80, CH-4056 Bas...
Author Institution: Institute of Physical Chemistry, University of BaselThe electronic spectra of a ...
Author Institution: Department of Chemistry, University of BaselThe carbon chains $C_{n} H (n=2-6)$ ...
Author Institution: Department of Chemistry, University of BaselThe carbon chains $C_{n} H (n=2-6)$ ...
International audienceAbstract Only 4 of the diffuse interstellar bands (DIBs) are currently account...
Measurement of the Π3−Π3 transition of C6H+ in the gas phase near 19486 cm−1 is reported. The experi...
Recent low-temperature laboratory measurements and astronomical observations have proved that the fu...
Our research has focused on the measurement of the electronic spectra of unstable molecules which ar...
Measurement of the 3Π-3Π transition of C6H+ in the gas phase near 19486 cm−1 is reported. The experi...
Recent low-temperature laboratory measurements and astronomical observations have proved that the fu...
Recent low-temperature laboratory measurements and astronomical observations have proved that the fu...
Recent low-temperature laboratory measurements and astronomical observations have proved that the fu...
The gas phase spectrum of the cyclic C18 molecule recorded in the laboratory at a temperature typica...