Add to ORKGStereochemically pure methylsulfmates 3 and benzylsulfìnamides 4 are readily epimerized in the presence of hydrogen chloride and at the same time they can be transformed by sulfinate-sulfinamide interconversion. Formation of sulfinyl chlorides 2 as intermediates and their epimerization by rapid chloride anion exchange at sulfur atom is proposed. The equilibrated ratio between epimers 2a and 2b determines the enantioselectivity of these processes
New chiral beta-(sulfonylamino)sulfinylimidates are synthesized in high overall yield and excellent ...
Sulfinimines are important chiral auxiliaries for asymmetric synthesis of amines. Enantiopure sulfin...
New chiral beta-(sulfonylamino)sulfinylimidates are synthesized in high overall yield and excellent ...
Stereochemically pure methylsulfmates 3 and benzylsulfìnamides 4 are readily epimerized in the prese...
Chapter 1 This chapter offers an extensive introduction about alkyl halides, an important class of i...
Chapter 1 This chapter offers an extensive introduction about alkyl halides, an important class of i...
Easily accessible chiral sulfinamide 2 has been developed as the first highly efficient and enantios...
Diazo sulfonylamidines readily undergo enantioselective oxygen transfer from sulfur to carbon atom i...
alpha-Alkylation of N-sulfinyl imidates, prepared via condensation of tert-butanesulfinamide with or...
alpha-Alkylation of N-sulfinyl imidates, prepared via condensation of tert-butanesulfinamide with or...
This thesis reports findings in two projects utilising sulfur as a chiral auxiliary in asymmetric sy...
alpha-Alkylation of N-sulfinyl imidates, prepared via condensation of tert-butanesulfinamide with or...
The synthesis of optically active sulfinic acid esters has been accomplished by the acid catalyzed a...
The synthesis of optically active sulfinic acid esters has been accomplished by the acid catalyzed a...
Despite the early understanding of the concept of chirality, a couple of decades ago, drugs containi...
New chiral beta-(sulfonylamino)sulfinylimidates are synthesized in high overall yield and excellent ...
Sulfinimines are important chiral auxiliaries for asymmetric synthesis of amines. Enantiopure sulfin...
New chiral beta-(sulfonylamino)sulfinylimidates are synthesized in high overall yield and excellent ...
Stereochemically pure methylsulfmates 3 and benzylsulfìnamides 4 are readily epimerized in the prese...
Chapter 1 This chapter offers an extensive introduction about alkyl halides, an important class of i...
Chapter 1 This chapter offers an extensive introduction about alkyl halides, an important class of i...
Easily accessible chiral sulfinamide 2 has been developed as the first highly efficient and enantios...
Diazo sulfonylamidines readily undergo enantioselective oxygen transfer from sulfur to carbon atom i...
alpha-Alkylation of N-sulfinyl imidates, prepared via condensation of tert-butanesulfinamide with or...
alpha-Alkylation of N-sulfinyl imidates, prepared via condensation of tert-butanesulfinamide with or...
This thesis reports findings in two projects utilising sulfur as a chiral auxiliary in asymmetric sy...
alpha-Alkylation of N-sulfinyl imidates, prepared via condensation of tert-butanesulfinamide with or...
The synthesis of optically active sulfinic acid esters has been accomplished by the acid catalyzed a...
The synthesis of optically active sulfinic acid esters has been accomplished by the acid catalyzed a...
Despite the early understanding of the concept of chirality, a couple of decades ago, drugs containi...
New chiral beta-(sulfonylamino)sulfinylimidates are synthesized in high overall yield and excellent ...
Sulfinimines are important chiral auxiliaries for asymmetric synthesis of amines. Enantiopure sulfin...
New chiral beta-(sulfonylamino)sulfinylimidates are synthesized in high overall yield and excellent ...