Empirical thesis.Includes bibliographical references.Chapter 1. Introduction -- Chapter 2. Ru(II) complexes of hemilabile pincer ligands for catalysed transfer hydrogenation reactions -- Chapter 3. Ni(II) complexes of hemilabile pincer ligands for catalysed Kumada cross coupling reactions -- Chapter 4. Gold(I) and Gold(III) complexes of hemilabile pincer ligands for catalysed activation of alkynes -- Chapter 5. Conclusions and future work -- Chapter 6. Experimental -- Appendices.This thesis describes the synthesis of new Ag(I), Ru(II), Ni(II), Au(I) and Au(III) complexes containing an imidazolyl-pyrazolyl ligand motif (NCNMe- methylene linker, and NCNEt- ethylene linker). The synthesised complexes were tested as catalysts for a number of or...
1-Methyl-3-(2-((pyridin-2-ylmethylene)amino)ethyl)-1H-imidazol-3-ium bromide was prepared and used a...
In the last century, no less than five nobel prizes have been awarded for the construction of carbon...
The development of procedures for the synthesis of valuable organic molecules constitutes an importa...
A series of Ru(II) complexes were synthesised based on a hemilabile pyrazole-N-heterocyclic carbene ...
In this thesis, a series of symmetrical and unsymmetrical pincer ligands are synthesised and explore...
In this thesis, a series of symmetrical and unsymmetrical pincer ligands are synthesised and explore...
Over the past decade, late transition metal complexes bearing 2,6-bis(imino)pyridyl ligands, [N3], a...
Over the past decade, late transition metal complexes bearing 2,6-bis(imino)pyridyl ligands, [N3], a...
A variety of new metal complexes of tridentate pincer ligands are reported. An emphasis on combinati...
145 p.This thesis is divided into two parts. In part one, several nitrone-based bidentate and triden...
145 p.This thesis is divided into two parts. In part one, several nitrone-based bidentate and triden...
Metal-ligand cooperation (MLC) has played an important role in the development of new green homogene...
The understanding of small molecule activation by transition metal complexes is key for many fields ...
1-Methyl-3-(2-((pyridin-2-ylmethylene)amino)ethyl)-1H-imidazol-3-ium bromide was prepared and used a...
[[abstract]]The silver complex of PCNHCP was identified as [Ag3(μ-Cl)(PCNHCP)2]Cl2 (1). Anion exchan...
1-Methyl-3-(2-((pyridin-2-ylmethylene)amino)ethyl)-1H-imidazol-3-ium bromide was prepared and used a...
In the last century, no less than five nobel prizes have been awarded for the construction of carbon...
The development of procedures for the synthesis of valuable organic molecules constitutes an importa...
A series of Ru(II) complexes were synthesised based on a hemilabile pyrazole-N-heterocyclic carbene ...
In this thesis, a series of symmetrical and unsymmetrical pincer ligands are synthesised and explore...
In this thesis, a series of symmetrical and unsymmetrical pincer ligands are synthesised and explore...
Over the past decade, late transition metal complexes bearing 2,6-bis(imino)pyridyl ligands, [N3], a...
Over the past decade, late transition metal complexes bearing 2,6-bis(imino)pyridyl ligands, [N3], a...
A variety of new metal complexes of tridentate pincer ligands are reported. An emphasis on combinati...
145 p.This thesis is divided into two parts. In part one, several nitrone-based bidentate and triden...
145 p.This thesis is divided into two parts. In part one, several nitrone-based bidentate and triden...
Metal-ligand cooperation (MLC) has played an important role in the development of new green homogene...
The understanding of small molecule activation by transition metal complexes is key for many fields ...
1-Methyl-3-(2-((pyridin-2-ylmethylene)amino)ethyl)-1H-imidazol-3-ium bromide was prepared and used a...
[[abstract]]The silver complex of PCNHCP was identified as [Ag3(μ-Cl)(PCNHCP)2]Cl2 (1). Anion exchan...
1-Methyl-3-(2-((pyridin-2-ylmethylene)amino)ethyl)-1H-imidazol-3-ium bromide was prepared and used a...
In the last century, no less than five nobel prizes have been awarded for the construction of carbon...
The development of procedures for the synthesis of valuable organic molecules constitutes an importa...