This bachelor thesis deals with the basic physical principles of dielectrics as well as the description of the phenomenon of dielectric absorption. The work presents diagnostic methods that use this phenomenon, based on the events taking place in the dielectric after the connection of DC voltage. Furthermore, the work deals with diagnostic methods for determining the state of insulation of various high-voltage electrical equipment. The work also deals with the properties and parameters of electrical insulating materials - specifically polymers. We obtain these parameters using the mentioned diagnostic methods. By knowing these parameters, we achieve enough information about the insulation to determine its condition and prevent possible dama...