Rheological Behaviour of PP Nanocomposites by Extrusion Process

The effect of organophilic clay (C15A) in PP compatibilized polymer (PP/PP-g-MA) through rheological experimental results is presented. This study focusses on the description of the rheological behaviour of the organophilic layers along the screws of a twin screw extruder by melting process, varying the screw profile as well as the processing conditions, namely screw speed, temperature and feed rate. Different levels of dispersion were found along the screws for all conditions and positions analyzed by rheology. The qualitative analysis of the images obtained by transmission electron microscopy, reinforced the results. Furthermore, the effects of the processing conditions on dispersion of C15A layers along the screw profile are analyzed using multiple linear regression techniques. The results show statistically significant differences of all rheology measures for all the processing conditions and positions along the extruder.