Multistage evolution of the neoarchean (ca. 2.7 Ga) Igarape Cinzento (GT-46) iron oxide copper-gold deposit, Cinzento shear zone, Carajas province, Brazil

The Igarape Cinzento (GT-46) iron oxide copper-gold deposit is located in the northwestern part of the Cinzento shear zone in Carajas province, Brazil. Copper mineralization in the deposit is hosted by a hydrothermally altered metavolcanosedimentary sequence that consists of interlayered amphibolites, (actinolite)-biotite schists, almandine-biotite schists, and metamorphosed banded iron formations, intruded by granitoids (tonalite to granite) and mafic dikes. The complex evolution of the deposit involved (1) deposition of a volcanosedimentary sequence (2774 +/- 19 Ma U-Pb zircon), (2) a tectonometamorphic event (D-n = upper amphibolite facies), restricted in time between 2.77 and 2.72 Ga, (3) development of the Cinzento shear zone (Dn+1) at 2.72 Ga, with associated hydrothermal activity and deposit formation, (4) superimposed hydrothermal events (ca. 2.6 and 2.5 Ga), and (5) granitoid emplacement at ca 2.5 Ga in the region. The GT-46 deposit is the result of overprinting hydrothermal stages with at least two distinct mineralization events. Variations in alteration styles are a consequence of changes in the mechanisms of fluid control, first regulated by ductile deformation and later by brittle fracturing. Early hydrothermal alteration is characterized by zones of sodic-calcic and potassic alteration as well as iron metasomatism with associated disseminated mineralization I, controlled by ductile structures (chalcopyrite-bornite-magnetite, 2718 +/- 56 Ma, Re-Os molybdenite). Veins and breccias with chalcopyrite-magnetite(-chlorite-calcite-quartz) represent an overprinting episode of mineralization (II) at ca. 2.6 Ga. Late alteration stages (ca. 2.5 Ga) represent fluid remobilization with chloritization zones and crystal growth spatially related to pegmatite intrusions. Re-Os molybdenite ages of 2503 +/- 51 and 2449 +/- 44 Ma provide evidence for younger episodes of hydrothermal fluid circulation in the deposit. Fluid inclusion study reveals aqueous-saturated, highly saline (32 -> 50 wt % NaC(l )equiv, total homogenization temperature [T-h(t)] = 203 degrees -> 450 degrees C) and carbonic fluids (CO2 melting temperature [T-mCO2] = -56.3 degrees to -54.5 degrees C) for early alteration zones and saline (2.1-27.5 wt % NaCl equiv, T-ht = 153.3 degrees-215.5 degrees C) solutions for late alteration zones. These data provide evidence for several alternative fluids involved in the evolution of the deposit: (1) hypersaline fluids derived from hydrothermal-magmatic brines or evaporative brines/evaporite-derived fluids, (2) saline solutions generated by progressive dilution of primary hypersaline fluids with shallower, colder, and less saline fluids (e.g., meteoric, seawater), and (3) carbonic components sourced from magmatic fluids, devolatilization of carbonate units and, partially, metamorphic fluids. Sulfur is interpreted to have been leached from country rocks in the earlier hydrothermal stages (mineralization II, delta S-34 = 0.01-1.99 parts per thousand), and to have come from mixed granitic and external oxidized sources for later overprinting events (mineralization II, delta S-3(4)= 9.75-11.25 parts per thousand). These data provide evidence for the recurrence of hydrothermal activity, indicating the existence of different potential sources of metals and sulfur during the evolution of the deposit1141134CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQFUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP457689/2014-52016/13162-7This research was funded by the Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) (2016/13162-7), Conselho Nacional de Desenvolvimento Científico e Tec-nológico (CNPq) (457689/2014-5), and a Fundo de Apoio ao Ensino, Pesquisa e Extensão (FAEPEX)/Pró-Reitoria de Pesquisa da Unicamp (PRP)/UNICAMP (PAPIDIC_44/15) scholarship for the first autho