Using a palladium catalyst supported by DrewPhos, the alkylation of monochlorosilanes with primary and secondary alkylmagnesium halides is now possible. Arylation with sterically demanding aromatic magnesium halides is also enabled. This transformation overcomes the high bond strength of the Si–Cl bond (113 kcal/mol) and is a rare example of a transition-metal catalyzed process involving its activation. Because of the availability of both chlorosilanes and organomagnesium halide reagents, this method allows for the preparation of a wide range of alkyl and aryl silanes.Supplementary material: [http://cherry.chem.bg.ac.rs/handle/123456789/3924]Related to accepted version: [http://cherry.chem.bg.ac.rs/handle/123456789/3925
The palladium-catalyzed silylation of aryl chlorides with silylsilatranes proceeds under activator-f...
The palladium-catalyzed direct cross-coupling of a range of organic chlorides and bromides with the ...
The palladium-catalyzed direct cross-coupling of a range of organic chlorides and bromides with the ...
Using a palladium catalyst supported by DrewPhos, the alkylation of monochlorosilanes with primary a...
We report the first example of a silyl-Negishi reaction between secondary zinc organometallics and s...
We report the first example of a silyl-Negishi reaction between secondary zinc organometallics and s...
The development of alkali-metal arylsilanolates as notable organometallic reagents for the preparati...
The nickel or palladium catalyzed cross-coupling reac-tions of organic halides or triflates with alk...
Triorganosilanes, which possess two aryl groups on the silicon atom, undergo the palladium-catalyzed...
PtCl2, AgOTf or Hg(CF3CO2)2 (1 - 5 mol%) efficiently catalyze the addition of allyldimethylchlorosil...
587 p.Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2007.Mechanistic investigations of...
587 p.Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2007.Mechanistic investigations of...
PtCl<sub>2</sub>, AgOTf or Hg(CF<sub>3</sub>CO<sub>2</sub>)<sub>2</sub> (1 - 5 mol%) efficiently cat...
Organolithium compounds are amongst the most important organometallic reagents and frequently used i...
Organolithium compounds are amongst the most important organometallic reagents and frequently used i...
The palladium-catalyzed silylation of aryl chlorides with silylsilatranes proceeds under activator-f...
The palladium-catalyzed direct cross-coupling of a range of organic chlorides and bromides with the ...
The palladium-catalyzed direct cross-coupling of a range of organic chlorides and bromides with the ...
Using a palladium catalyst supported by DrewPhos, the alkylation of monochlorosilanes with primary a...
We report the first example of a silyl-Negishi reaction between secondary zinc organometallics and s...
We report the first example of a silyl-Negishi reaction between secondary zinc organometallics and s...
The development of alkali-metal arylsilanolates as notable organometallic reagents for the preparati...
The nickel or palladium catalyzed cross-coupling reac-tions of organic halides or triflates with alk...
Triorganosilanes, which possess two aryl groups on the silicon atom, undergo the palladium-catalyzed...
PtCl2, AgOTf or Hg(CF3CO2)2 (1 - 5 mol%) efficiently catalyze the addition of allyldimethylchlorosil...
587 p.Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2007.Mechanistic investigations of...
587 p.Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2007.Mechanistic investigations of...
PtCl<sub>2</sub>, AgOTf or Hg(CF<sub>3</sub>CO<sub>2</sub>)<sub>2</sub> (1 - 5 mol%) efficiently cat...
Organolithium compounds are amongst the most important organometallic reagents and frequently used i...
Organolithium compounds are amongst the most important organometallic reagents and frequently used i...
The palladium-catalyzed silylation of aryl chlorides with silylsilatranes proceeds under activator-f...
The palladium-catalyzed direct cross-coupling of a range of organic chlorides and bromides with the ...
The palladium-catalyzed direct cross-coupling of a range of organic chlorides and bromides with the ...