Synthesis and characterization of a supported Pd complex on carbon nanofibers for the selective decarbonylation of stearic acid to 1-heptadecene: the importance of subnanometric Pd dispersion

13 figures, 6 tables.-- Supplementary informationProduction of linear α-olefins from renewable sources is gaining increasing attention because it allows the transition from the current petrochemical synthesis route to a more sustainable scenario. In this work, we describe the synthesis and characterization of an innovative catalyst based on a di-μ-chloro-bis[palladium(II) anthranilate] complex highly dispersed by incipient wetness impregnation over acyl chlorinated carbon nanofibers. The subnanometric dispersion of the metal complex allowed higher catalytic efficiency for the selective decarbonylation of stearic acid to 1-heptadecene as compared to the reference homogenous catalyst. The best catalytic performance (90 mol% selectivity, 71 mol% conversion, and TON = 484) was achieved under mild reaction conditions (atmospheric pressure, 140 °C) with a Pd loading in solution of 0.14 mol%. The post-mortem catalyst characterization and the recyclability tests evidenced the high stability of the catalyst. The highly dispersed catalyst developed in this work provides new opportunities in the rational design of more efficient catalytic systems for the sustainable transformation of fatty acids.The authors are grateful for the financial support from FEDER and the Spanish Economy and Competitiveness Ministry (MINECO) (ENE2017-83854-R). EO acknowledges MINECO for her PhD grant under the frame of the aforementioned project. The authors gratefully acknowledge “Laboratorio de Microscopías Avanzadas” at “Instituto de Nanociencia de Aragón−Universidad de Zaragoza” for offering access to their microscope and expertise. W. Henao acknowledges the financial support from the grant sponsored by Fundación Carolina (Madrid, Spain) and the University of Zaragoza.We acknowledge support of the publication fee by the CSIC Open Access Publication Support Initiative through its Unit of Information Resources for Research (URICI).Peer reviewe