The paper presents Large Eddy Simulations (LES) of mass transfer and fluid flow evolutions of a submerged rectangular free jet of air in the range of Reynolds numbers from Re = 3400 to Re = 22,000, with the Reynolds number, Re, defined with the hydraulic diameter of the rectangular slot, of height H. The numerical simulations are 3D for Re = 3400 and 6800, while 2D for Re = 10,400 and 22,000 to reduce computational time costs. The average and instant LES numerical simulations are compared with the concentration visualizations, obtained with the Particle Image Velocimetry (PIV) technique, and the fluid dynamics variables, velocity and turbulence, measured with the PIV technique and the Hot Film Anemometry (HFA). In the numerical simulations,...