Dielectric Properties and Electromagnetic Wave Absorbing Performance of Single-Source-Precursor Synthesized Mo4.8Si3C0.6/SiC/Cfree Nanocomposites with an In Situ Formed Nowotny Phase

For the first time, dielectric properties and electromagnetic wave (EMW) absorbing performance of single-source-precursor derived Mo4.8Si3C0.6/SiC/C-free ceramic nanocomposites with a highly electrically conductive intermetallic Nowotny phase (NP, i.e., Mo4.8Si3C0.6) are reported. High-temperature phase evolution of the nanocomposites reveals that free carbon (C-free) plays a crucial role in the in situ formation of the NP, indicating that the microstructure of the nanocomposites can be tailored via molecular design of the single-source precursors. Compared with SiC/C-free and MoSi2/SiC/C-free nanocomposites obtained under the same conditions, the Mo4.8Si3C0.6/SiC/C-free nanocomposites exhibit significantly enhanced EMW absorbing performance. A minimum reflection loss (RL) of -59 dB was achieved at 8 GHz for the thickness of 2.46 mm, proving the superiority of the Mo4.8Si3C0.6/SiC/C-free nanocomposite as an outstanding EMW absorbing material. On the basis of our previous discovery that the Mo4.8Si3C0.6 embedded in a SiC-based matrix with high specific surface area exhibits excellent electrocatalytic properties suitable for the electrochemical hydrogen evolution reaction, the present results prove that Mo4.8Si3C0.6/SiC/C-free nanocomposites have to be considered as novel multifunctional materials with tailorable microstructure and excellent performance in two different fields including electrochemical water splitting and EMW absorption