© The Royal Society of Chemistry 2015. The extension of our simple model for predicting the propeller configuration of a triphenylphosphine ligand co-ordinated to achiral metal centres to include stereogenic metal systems is described. By considering nadir energy planes (NEP's) and a series of rigid-body calculations, a model has been developed to reliably predict the configuration of the triphenylphosphine rotor of stereogenic metal complexes. For complexes of the form [M(η 5 -C 5 H 5 )(PPh 3 )(L 1 )(L 2 )], where it is assumed that L 1 is larger than L 2 , the configuration of the triphenylphosphine rotor may be predicted by viewing a Newman projection along the L 1 -M bond. In the orientation where the PPh 3 unit is pointing vertically ...
The stereoelectronic features of the pentacyclic phosphane (1S,4R,4aS,5aR,6R,9S,9aS,10aR)-4,6,11,11,...
An empirical approach to the study of phosphine compounds was completed using Molecular Mechanics 2 ...
The Tolman cone angle (θ), the par excellence descriptor of the steric measure of a phosphine, has b...
© The Royal Society of Chemistry 2015. The extension of our simple model for predicting the propell...
The novel concept of nadir energy planes has been used to illuminate the principles governing the pr...
The novel concept of nadir energy planes has been used to illuminate the principles governing the pr...
In half-sandwich compounds of the type [Cp*(MLLPPh3)-L-1-P-2] the PPh3 propeller is stabilized by at...
The conformational analyses of PPh3 1 and the representative achiral metal complexes [Al(PPh3)(Me)3]...
The conformational analyses of PPh3 1 and the representative achiral metal complexes [Al(PPh3)(Me)3]...
International audienceThe structure of cis-[Mo(CO)4(PPh3)2] 1 was determined by F. A. Cotton, D. J. ...
The conformations of a series of organophosphine oxides, OP(CH<sub>3</sub>)<sub>2</sub>R, where R =...
The specific rotation of (RFe,R,M)-4 switches sign upon epimerisation to (RFe,S,P)-5. X-Ray crystall...
The purpose of this project was to extend earlier work done by Mian Chin and Greg Durst, correcting ...
PNP pincer ligands stabilise diamagnetic base metal catalysts, and much effort has been invested in ...
The architecture of the triphenylphosphine propeller in Cr-PPh3 complexes and in the compounds trans...
The stereoelectronic features of the pentacyclic phosphane (1S,4R,4aS,5aR,6R,9S,9aS,10aR)-4,6,11,11,...
An empirical approach to the study of phosphine compounds was completed using Molecular Mechanics 2 ...
The Tolman cone angle (θ), the par excellence descriptor of the steric measure of a phosphine, has b...
© The Royal Society of Chemistry 2015. The extension of our simple model for predicting the propell...
The novel concept of nadir energy planes has been used to illuminate the principles governing the pr...
The novel concept of nadir energy planes has been used to illuminate the principles governing the pr...
In half-sandwich compounds of the type [Cp*(MLLPPh3)-L-1-P-2] the PPh3 propeller is stabilized by at...
The conformational analyses of PPh3 1 and the representative achiral metal complexes [Al(PPh3)(Me)3]...
The conformational analyses of PPh3 1 and the representative achiral metal complexes [Al(PPh3)(Me)3]...
International audienceThe structure of cis-[Mo(CO)4(PPh3)2] 1 was determined by F. A. Cotton, D. J. ...
The conformations of a series of organophosphine oxides, OP(CH<sub>3</sub>)<sub>2</sub>R, where R =...
The specific rotation of (RFe,R,M)-4 switches sign upon epimerisation to (RFe,S,P)-5. X-Ray crystall...
The purpose of this project was to extend earlier work done by Mian Chin and Greg Durst, correcting ...
PNP pincer ligands stabilise diamagnetic base metal catalysts, and much effort has been invested in ...
The architecture of the triphenylphosphine propeller in Cr-PPh3 complexes and in the compounds trans...
The stereoelectronic features of the pentacyclic phosphane (1S,4R,4aS,5aR,6R,9S,9aS,10aR)-4,6,11,11,...
An empirical approach to the study of phosphine compounds was completed using Molecular Mechanics 2 ...
The Tolman cone angle (θ), the par excellence descriptor of the steric measure of a phosphine, has b...