An efficient and operationally simple method for the reduction of sulfoxides to sulfides has been developed using bis(catecholato)diboron (B₂cat₂) as a reducing agent. The present method accommodates various functional groups which are generally prone to reduction: halides, alkynes, carbonyls, nitriles, and heterocycles are totally intact, and only sulfoxide moieties undergo reduction chemoselectively. Moreover, the remaining diboron and the resulting boron‐containing wastes are readily removable, the practicality of this protocol being thus demonstrated
Design, synthesis and structural characterization of a series of diphenylacetylene derivatives beari...
It has been previously shown that benzenesulfonamide gives thiophenol and diphenyldisulfide upon Bir...
Protein persulfidation plays a role in redox signaling as an anti-oxidant. Dimers of amyloid β42 (Aβ...
Readily available aryldimethylsulfonium triflates react with zinc powder under nickel catalysis via ...
Reductive 1, 2-diboration of alkynes has been accomplished by means of sodium dispersion in the pres...
Regioselective difunctionalization of 2, 6-difluorophenols with aryl sulfoxides and nucleophiles has...
A mild and chemoselective three-component thioesterification using olefins, α-ketoacids, and element...
Treatment of aryl-fused bicyclo[4.2.0]octanols with an oxidant such as phenyliodine diacetate (PIDA)...
Abstract Several organosulfur compounds are present in the crude oil, and are required to be removed...
An S−N variant of the N−N‐based Fischer indole synthesis has been developed. Treatment of sulfonanil...
A conceptionally novel nucleophilic substitution approach to synthetically important alkyl bromides ...
The direct 2‐deoxyglycosylation of nucleophiles with glycals leads to biologically and pharmacologic...
Organic synthesis is performed based on precise choices of functional groups and reactions employed....
This one page article is an opinion on the sulfur vulcanization of rubber. It states that combining ...
Various 2-substituted-1,3-dithiane oxides (1-oxide and 1,3-dioxide) have been metalated and reacted ...
Design, synthesis and structural characterization of a series of diphenylacetylene derivatives beari...
It has been previously shown that benzenesulfonamide gives thiophenol and diphenyldisulfide upon Bir...
Protein persulfidation plays a role in redox signaling as an anti-oxidant. Dimers of amyloid β42 (Aβ...
Readily available aryldimethylsulfonium triflates react with zinc powder under nickel catalysis via ...
Reductive 1, 2-diboration of alkynes has been accomplished by means of sodium dispersion in the pres...
Regioselective difunctionalization of 2, 6-difluorophenols with aryl sulfoxides and nucleophiles has...
A mild and chemoselective three-component thioesterification using olefins, α-ketoacids, and element...
Treatment of aryl-fused bicyclo[4.2.0]octanols with an oxidant such as phenyliodine diacetate (PIDA)...
Abstract Several organosulfur compounds are present in the crude oil, and are required to be removed...
An S−N variant of the N−N‐based Fischer indole synthesis has been developed. Treatment of sulfonanil...
A conceptionally novel nucleophilic substitution approach to synthetically important alkyl bromides ...
The direct 2‐deoxyglycosylation of nucleophiles with glycals leads to biologically and pharmacologic...
Organic synthesis is performed based on precise choices of functional groups and reactions employed....
This one page article is an opinion on the sulfur vulcanization of rubber. It states that combining ...
Various 2-substituted-1,3-dithiane oxides (1-oxide and 1,3-dioxide) have been metalated and reacted ...
Design, synthesis and structural characterization of a series of diphenylacetylene derivatives beari...
It has been previously shown that benzenesulfonamide gives thiophenol and diphenyldisulfide upon Bir...
Protein persulfidation plays a role in redox signaling as an anti-oxidant. Dimers of amyloid β42 (Aβ...