Learning environment and school situations can trigger several affective states, which can include extreme feelings such as intense happiness or hatred. This study, based on a random sample (N= 26,470) of the Italian tenth grade students investigated: (1) the multilevel impact of individual and group characteristics on students’ psychological well-being; (2) the mediational role of autonomy support and peer relatedness. In the first part of the study the following factors were considered at the individual level: gender, immigrant background (first-generation and second-generation immigrants), socioeconomic background and achievement before entering high school. At the group level, the analysis included class size and compositional variable...